(1S)-(+)-Camphor-10-sulphonic acid NEW
Price | $1 |
Package | 1kg |
Min. Order: | 1kg |
Supply Ability: | 50000kg/month |
Update Time: | 2024-08-28 |
Product Details
Product Name: (1S)-(+)-Camphor-10-sulphonic acid | CAS No.: 3144-16-9 |
EC-No.: 221-554-1 | Min. Order: 1kg |
Purity: 99% | Supply Ability: 50000kg/month |
Release date: 2024/08/28 |
CAS: | 3144-16-9 |
MF: | C10H16O4S |
MW: | 232.3 |
EINECS: | 221-554-1 |
Product Categories: | chiral;Pharmaceutical Intermediates;FINE Chemical & INTERMEDIATES;Chiral Compounds;Bicyclic Monoterpenes;Biochemistry;for Resolution of Bases;Optical Resolution;Reagents for Oligosaccharide Synthesis;Synthetic Organic Chemistry;Terpenes;Peptide;Sulfur & Selenium Compounds;3144-16-9;3597-91-9 |
Mol File: | 3144-16-9.mol |
Melting point | 196-200 °C (dec.)(lit.) |
alpha | 22 º (589nm, c=20, H2O 25 ºC) |
Boiling point | 344.46°C (rough estimate) |
density | 1.2981 (rough estimate) |
refractive index | 21.5 ° (C=5, H2O) |
storage temp. | Store below +30°C. |
solubility | Exhibit moderate solubility in HCCl. |
pka | 1.17±0.50(Predicted) |
form | Crystalline Powder |
color | White to off-white |
PH | 0.3 (200g/l, H2O) |
optical activity | [α]20/D +21.5±1°, c = 10% in H2O |
Water Solubility | SOLUBLE |
Sensitive | Hygroscopic |
Merck | 14,1734 |
BRN | 2809675 |
Stability: | Stable. Protect from moisture. Incompatible with strong oxidizing agents, strong bases. |
InChIKey | MIOPJNTWMNEORI-GMSGAONNSA-N |
CAS DataBase Reference | 3144-16-9(CAS DataBase Reference) |
EPA Substance Registry System | Bicyclo[2.2.1]heptane-1-methanesulfonic acid, 7,7-dimethyl-2-oxo-, (1S,4R)- (3144-16-9) |
Synthesis | (1S)-(+)-Camphor-10-sulphonic acid can be obtained from natural camphor by brominated sulfonation . |
Chemical Properties | white to light beige powder |
Uses | (1S)-(+)-Camphor-10-sulfonic acid is used as stabilizer. (+)-(1S)-camphor-10-sulfonic acid being a very effective resolving agent. . Chiral polyaniline(PANI) nanofibers were synthesized via facilely potentiostatic electropolymerization method without template in the presence of(1S)-(+)camphor-10-sulfonic acid(D-CSA) or(1R)-(-)camphor-10-sulfonic acid(L-CSA) as the dopant. Synthesis of QUATs derived from (1S)-(+)camphor-10-sulfonic acid. |
Uses | Used as a resolving agent, and as a catalyst for coupling dipeptides. |
Definition | ChEBI: (S)-camphorsulfonic acid is the S enantiomer of camphorsulfonic acid. It is a conjugate acid of a (S)-camphorsulfonate. It is an enantiomer of a (R)-camphorsulfonic acid. |
Purification Methods | Crystallise the acid from ethyl acetate and dry it under vacuum (deliquescent). [Loudon J Chem Soc 823 1933, Komppa J Prakt Chem 162 19 1943, Beilstein 11 IV 642.] See above for RS-isomer. |
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