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Postion:Product Catalog >Organic Chemistry>Carboxylic acids and derivatives>Carboxylic Acid Anhydrides>3,3',4,4'-Benzophenonetetracarboxylic dianhydride
3,3',4,4'-Benzophenonetetracarboxylic dianhydride
  • 3,3',4,4'-Benzophenonetetracarboxylic dianhydride

3,3',4,4'-Benzophenonetetracarboxylic dianhydride

Price $1
Package 1kg
Min. Order: 1kg
Supply Ability: 100KG
Update Time: 2019-07-06

Product Details

Product Name: 3,3',4,4'-Benzophenonetetracarboxylic dianhydride CAS No.: 2421-28-5
Min. Order: 1kg Purity: 99%
Supply Ability: 100KG Release date: 2019/07/06
Number:: AD68
 
3,3',4,4'-Benzophenonetetracarboxylic dianhydride Basic information
Product Name: 3,3',4,4'-Benzophenonetetracarboxylic dianhydride
Synonyms: 1,3-Isobenzofurandione, 5,5'-carbonylbis-;3,3',4,4'-Benzophenonetetracarboxylic acid dianhydride;3,3',4,4'-Tetracarboxybenzophenone dianhydride;3,3’,4,4’-benzophenonetetracarboxylicaciddianhydride;3-Isobenzofurandione,5,5’-carbonylbis-1;4,4'-Carbonylbis[phthalic anhydride];4,4'-Diphthalic anhydride ketone;5,5’-carbonylbis-3-isobenzofurandione
CAS: 2421-28-5
MF: C17H6O7
MW: 322.23
EINECS: 219-348-1
Product Categories: pharmacetical;Aromatic Tetracarboxylic Dianhydrides (for High-Performance Polymer Research);Benzophenones (for High-Performance Polymer Research);Functional Materials;Reagent for High-Performance Polymer Research;fine chemicals, specialty chemicals, intermediates, electronic chemical, organic synthesis, pharmaceutical intermediates;fine chemicals, specialty chemicals, intermediates, electronic chemical, organic synthesis, functional materials
Mol File: 2421-28-5.mol
Article illustration
 
3,3',4,4'-Benzophenonetetracarboxylic dianhydride Chemical Properties
Melting point  218-222 °C(lit.)
Boiling point  320°C 5mm
density  1,57 g/cm3
vapor density  1.4 (vs air)
vapor pressure  <0.1 mm Hg ( 0 °C)
refractive index  1.6380 (estimate)
Fp  324 °C
solubility  DMF: 0.1 g/mL, clear
form  Needles or Crystalline Powder
color  Off-white to brown
explosive limit 16%
Water Solubility  REACTS
Sensitive  Moisture Sensitive
λmax 580nm(CH3CN)(lit.)
Sublimation  220-230 ºC
BRN  761777
NIST Chemistry Reference Bis-(3-phthalyl anhydride) ketone(2421-28-5)
EPA Substance Registry System 1,3-Isobenzofurandione, 5,5'-carbonylbis-(2421-28-5)
 
Safety Information
Hazard Codes  Xi
Risk Statements  36/37
Safety Statements  25
WGK Germany  1
21
TSCA  Yes
HS Code  29183000
MSDS Information
Provider Language
BTDA English
ACROS English
SigmaAldrich English
ALFA English
 
3,3',4,4'-Benzophenonetetracarboxylic dianhydride Usage And Synthesis
Chemical Properties white crystall powder
Uses BTDA is important monomer of polyimide, and used for production of polyimide material. The material has high temperature resistance, low temperature resistance, corrosion resistance, radiation resistance, insulation, shock resistance, excellent performance. Can be made into structure parts, laminates, films, adhesives, coatings, insulation materials and reinforcing material, etc., can be widely used in the field of aerospace, electrical / electronics, shipbuilding, automobile, precision machinery.
Uses Used in the synthesis of polyimides.
Purification Methods The main impurity is the free acid formed by hydrolysis (check for OH bands in the IR). This can be converted to the dianhydride by treating with Ac2O (molar ratio of 4 to 1 of acid), heating at 110-120o for 1.5 to 2hours, cooling to 0—5o and collecting the dianhydride. This is then dissolved in hot dioxane or Me2CO, filtered and cooled to 10—15o. The moisture sensitive solid is collected and dried at 120—130o in vacuo. It has been sublimed at high vacuum. [Faberov et al. J Org Chem USSR 4 153 (English translation) 1968.]

Company Profile Introduction

Established in 2014,Career Henan Chemical Co. is a manufacturerspecializing in the sale of fine chemicals. Mainly deals in the sales of: Pharmaceutical intermediates OLED intermediates: Pharmaceutical intermediates; OLED intermediates;

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