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Postion:Product Catalog >Inorganic chemistry>Inorganic salts>Phosphide And metal phosphates>Calcium hypophosphite
Calcium hypophosphite
  • Calcium hypophosphite

Calcium hypophosphite

Price $1
Package 1KG
Min. Order: 1KG
Supply Ability: 100kg
Update Time: 2019-12-31

Product Details

Product Name: Calcium hypophosphite CAS No.: 7789-79-9
Min. Order: 1KG Purity: 99%
Supply Ability: 100kg Release date: 2019/12/31
name: Cassie369
Product Name:
Calcium hypophosphite
Synonyms:
Phosphinicacid,calciumsalt;CALCIUM HYPOPHOSPHITE;CALCIUM PHOSPHINATE;CALCIUM HYPOPHOSPHITE EXTRA PURE, DAC;Lime hypophosphite;CALCIUM HYPOPHOSPHITE TECHNICAL;CALCIUMHYPOPHOSPHITE,PURIFIED;Calcium hydrophosphite
CAS:
7789-79-9
MF:
CaO4P2
MW:
166.02
EINECS:
232-190-8
Product Categories:
-;Inorganics
Mol File:
7789-79-9.mol
Article illustration
 
Calcium hypophosphite Chemical Properties
Melting point 
decomposes [ALF93]
form 
white monoclinic crystals
Water Solubility 
Soluble in water. Practically insoluble in alcohol. Slightly soluble in glycerol
Sensitive 
Hygroscopic
Merck 
14,1675
InChIKey
XJPMAXXEWYLDCQ-UHFFFAOYSA-L
CAS DataBase Reference
7789-79-9(CAS DataBase Reference)
EPA Substance Registry System
Calcium hypophosphite (7789-79-9)
 
Safety Information
Hazard Codes 
F
Risk Statements 
11
Safety Statements 
7-15
RIDADR 
UN 3180 4.1/PG 2
WGK Germany 
3
TSCA 
Yes
HazardClass 
4.1
Hazardous Substances Data
7789-79-9(Hazardous Substances Data)
MSDS Information
Provider
Language
Calcium hypophosphite
English
SigmaAldrich
English
ALFA
English
 
Calcium hypophosphite Usage And Synthesis
Description
Calcium hypophosphite has the molecular formula of Ca(H2PO2)2 and the molecular weight of 170.0631 g/mol. This salt can be prepared by the aqueous reaction of the carbonate or oxide with H3PO2:
CaO + 2H3PO2 ? Ca(H2PO2)2
The salt is soluble in water (20 g/100 ml at 20°C) so that the solution must be evaporated to obtain crystals. Ca(H2PO2)2 has the CAS number of 7789-79-9 and the density of 1.59 g/cm3. It is composed of white square monoclinic crystalswhich are water soluble. It is insoluble in alcohol or ether.When heated to about 305°C, it disproportionates, forming calcium phosphate and phosphine:
Ca(H2PO2)2 + heat ? CaHPO3 + PH3
Chemical Properties
white monoclinic, prismatic crystal(s) or granular powder(s); used as a corrosion inhibitor and in medicine [MER06] [HAW93]
Physical properties
Calcium hypophosphite is relatively soluble in water, and when added to a solution of sodium hypophosphite, forms a double salt. Crystals were obtained by slow evaporation of the solution to form dodecahedra with well-developed {110} faces. The crystal structure of CaNa(H2PO2)3 belongs to the cubic system with space group, P213, Z = 4 and a = 9.721?. The structure consists of two kinds of octahedral groups, one with a calcium atom and the other with a sodium atom. Each atom of the hypophosphite ions is coordinated to each one of the calcium and sodium atoms to form the octahedral. This structure is, in general, typical of the salts of hypophosphorous acid.
Calcium hypophosphite is readily available commercially since its main usage, both industrially and in Research, has proven to be as a source of hypophosphite anions to form other hypophosphites.
Uses
As corrosion inhibitor; in nickel plating. Pharmaceutic aid (retards oxidation of ferrous salts).

Company Profile Introduction

Established in 2014,Career Henan Chemical Co. is a manufacturerspecializing in the sale of fine chemicals. Mainly deals in the sales of: Pharmaceutical intermediates OLED intermediates: Pharmaceutical intermediates; OLED intermediates;

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