Dihydrocoumarin NEW
| Price | Get Latest Price |
| Package | 25KG |
| Min. Order: | 1KG |
| Supply Ability: | 50000KG/month |
| Update Time: | 2023-08-26 |
Product Details
| Product Name: Dihydrocoumarin | CAS No.: 119-84-6 |
| EC-No.: 204-354-9 | Min. Order: 1KG |
| Purity: 99% | Supply Ability: 50000KG/month |
| Release date: 2023/08/26 |
| CAS: | 119-84-6 |
| MF: | C9H8O2 |
| MW: | 148.16 |
| EINECS: | 204-354-9 |
| Product Categories: | Coumarins |
| Mol File: | 119-84-6.mol |
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| Dihydrocoumarin Chemical Properties |
| Melting point | 24-25 °C (lit.) |
| Boiling point | 272 °C (lit.) |
| density | 1.169 g/mL at 25 °C (lit.) |
| vapor pressure | 13.6kPa at 20℃ |
| FEMA | 2381 | DIHYDROCOUMARIN |
| refractive index | n |
| Fp | >230 °F |
| storage temp. | Sealed in dry,2-8°C |
| solubility | Chloroform, Methanol (Sparingly) |
| form | Solid |
| Specific Gravity | 1.169 |
| color | Colourless to Off-White |
| Odor | at 10.00 % in dipropylene glycol. sweet tonka coumarinic coconut herbal cinnamon balsamic |
| Odor Type | tonka |
| Water Solubility | insoluble |
| JECFA Number | 1171 |
| BRN | 4584 |
| LogP | 1.82 at 25℃ |
| CAS DataBase Reference | 119-84-6(CAS DataBase Reference) |
| NIST Chemistry Reference | 2H-1-Benzopyran-2-one, 3,4-dihydro-(119-84-6) |
| EPA Substance Registry System | 3,4-Dihydrocoumarin (119-84-6) |
| Dihydrocoumarin Usage And Synthesis |
| Description | With a sweet, creamy, and herbal, fragrance, with a slightly burnt taste, dihydrocoumarin (DHC) is used as a flavoring agent in food, tobacco, soap, and perfume, etc. Its exotic flavor is well suited for caramel, nuts, dairy, vanilla, tropical fruit, and alcohol. It is a eukaryotic metabolite found in tonka beans grown in northern South America, from which it was isolated as early as the 1820s, as well as sweet clover. Other uses include as an organic solvent and pharmaceutical intermediary. It has been shown to influence the epigenetic process of human cells in vitro. |
| Sources | http://www.ebi.ac.uk/chebi/searchId.do?chebiId=CHEBI:16151 http://www.bojensen.net/EssentialOilsEng/EssentialOils29/EssentialOils29.htm#Tonka https://books.google.kg/books?id=pUEqBgAAQBAJ&pg=PA427&lpg=PA427&dq=dihydrocoumarin+uses&source=bl&ots=HTZrffvsXu&sig=GPGKqrMRXQaRJ-qgHk7aULeBmGw&hl=en&sa=X&redir_esc=y#v=onepage&q=dihydrocoumarin%20uses&f=false https://products.symrise.com/aroma-molecules/product-search/dihydrocoumarin/action/pdf/ http://www.lookchem.com/3-4-Dihydrocoumarin/ https://www.ncbi.nlm.nih.gov/pmc/articles/PMC1315280/ |
| Chemical Properties | Dihydrocoumarin forms colorless crystals (mp 24°C) with a sweet, herbal odor. Dihydrocoumarin is prepared by hydrogenation of coumarin, for example, in the presence of a Raney nickel catalyst. Another process employs the vapor-phase dehydrogenation of hexahydrocoumarin in the presence of Pd or Pt-Al2O3 catalysts . Hexahydrocoumarin is prepared by cyanoethylation of cyclohexanone and hydrolysis of the nitrile group, followed by ring closure to the lactone. |
| Chemical Properties | Dihydrocoumarin has an odor similar to coumarin at room temperature or reminiscent of nitrobenzene at higher temperature. It has a burning taste. |
| Occurrence | Reported found in Melilotus officinalis, from which it may be extracted by water distillation. |
| Uses | Hydrocoumarin can be used as a reagent to prepare splitomicin analogs as inhibitors of Sir2. |
| Uses | Dihydrocoumarin may be used as an analytical reference standard for the determination of the analyte in guaco extracts and pharmaceutical preparations, and various plant extracts by chromatography-based techniques and capillary electrophoresis. |
| Definition | ChEBI: A chromanone that is the 3,4-dihydro derivative of coumarin. |
| Preparation | Dihydrocoumarin is synthesized by reduction of coumarin under pressure in the presence of nickel at 160 to 200°C or in the presence of Pd-BaSO4 in alcoholic solution. |
| Synthesis Reference(s) | Tetrahedron Letters, 37, p. 4555, 1996 DOI: 10.1016/0040-4039(96)00902-1 |
| General Description | White to pale yellow clear oily liquid with a sweet odor. Solidifies around room temperature. |
| Air & Water Reactions | Solutions of the chemical in water are stable for less than two hours. Insoluble in water. |
| Reactivity Profile | Hydrocoumarin is a lactone (behaves as an ester). Esters react with acids to liberate heat along with alcohols and acids. Strong oxidizing acids may cause a vigorous reaction that is sufficiently exothermic to ignite the reaction products. Heat is also generated by the interaction of esters with caustic solutions. Flammable hydrogen is generated by mixing esters with alkali metals and hydrides. Hydrocoumarin may hydrolyze under alkaline or acidic conditions. |
| Fire Hazard | Hydrocoumarin is combustible. |
| Biochem/physiol Actions | Taste at 10 ppm |
Packing &shipping&Payment
Packing:25kg/drum
Shipping:by sea or by air
Payment:T/T,western union,moneygram
Packaging Details drum
Port:Tianjin
Lead Time :
Shipping:by sea or by air
Payment:T/T,western union,moneygram
Packaging Details drum
Port:Tianjin
Lead Time :
| Quantity(Kilograms) | 1 - 10000 | >10000 |
| Est. Time(days) | 5 | To be negotiated |
Company information
Hebei Mojin Biotechnology Co., Ltd, Our company is a professional in 4'-Methylacetophenone,Levamisole hydrochloride ,N-Methylformamide and other chemical reagents research and development production enterprises. Our business covers more than 30 countries, most of the big customers come from Europe, America and other countries in the world, we can guarantee the quality and price. In recent decades, with the efforts of all employees, we have established many cooperative companies in shandong, henan, guangdong and other places. Our corporate purpose is based on the market, enhance the strength, take the road of scientific and environmental sustainable development, relying on the country. Technology r & d center, increase the investment in r & d, based on the domestic market, expand the international market, manufacturing quality products, sincere service to the society, into a modern, ecological, scientific and technological enterprise world.
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Japan
- Since: 2017-12-08
- Address: Building A, Enjoy city, Zhongshan East Road, Shijiazhuang city, Hebei province
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