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Salicylhydroxamic acid NEW
Price | Get Latest Price |
Package | 25KG |
Min. Order: | 1KG |
Supply Ability: | 50000KG/month |
Update Time: | 2023-10-24 |
Product Details
Product Name: Salicylhydroxamic acid | CAS No.: 89-73-6 |
EC-No.: 201-934-3 | Min. Order: 1KG |
Purity: 99% | Supply Ability: 50000KG/month |
Release date: 2023/10/24 |
CAS: | 89-73-6 |
MF: | C7H7NO3 |
MW: | 153.14 |
EINECS: | 201-934-3 |
Product Categories: | Aromatics;Intermediates & Fine Chemicals;Hydroxylamines;Pharmaceuticals;Aroamtics;Miscellaneous Reagents;Aromatic Hydrazides, Hydrazines, Hydrazones and Oximes;Hydroxylamines (N-Substituted) |
Mol File: | 89-73-6.mol |
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Salicylhydroxamic acid Chemical Properties |
Melting point | 177 °C (dec.) (lit.) |
Boiling point | 276.03°C (rough estimate) |
density | 1.3585 (rough estimate) |
refractive index | 1.5500 (estimate) |
storage temp. | Sealed in dry,Room Temperature |
pka | pK (25°) 4.19 |
form | Fine Crystalline Powder |
color | Beige-pink |
Water Solubility | It is soluble in water. |
Merck | 14,8331 |
BRN | 1210520 |
Stability: | Stable. Incompatible with strong bases, strong oxidizing agents. Combustible. |
CAS DataBase Reference | 89-73-6(CAS DataBase Reference) |
EPA Substance Registry System | N,2-Dihydroxybenzamide (89-73-6) |
Salicylhydroxamic acid Usage And Synthesis |
Chemical Properties | It is a white needle crystal or off-white powder with a slow-heating melting point of 168°C. It is soluble in alcohol and ether and can be sublimated. When exposed to air, it progressively turns red. It is synthesized by combining methyl salicylate and hydroxylamine hydrochloride with sodium hydroxide, followed by acidification. |
Uses | Salicylhydroxamic acid is a collector with efficient chelating effect on rare metal oxide minerals. It is used in rare metal beneficiation and has the advantages of good selectivity and strong collecting power. Salicylhydroxamic acid is mainly used as a complexing agent or extractant for rare earth ore, copper oxide ore, lead-zinc oxide ore, gold ore, kaolin, etc., as well as organic synthesis intermediates. |
Definition | ChEBI: Salicylhydroxamic acid is a hydroxamic acid that is N-hydroxybenzamide carrying a phenolic hydroxy group at position 2. It has a role as an antibacterial drug, a trypanocidal drug, an EC 3.5.1.5 (urease) inhibitor and an EC 1.11.2.2 (myeloperoxidase) inhibitor. It is a member of phenols and a hydroxamic acid. |
Application | Salicylhydroxamic acid has various applications, such as: Synthesizing phenylboronic acid-based bioconjugates for chromatographic use. Acting as a ligand to create complexes of Fe(III), Cu(II), Ni(II), and Zn(II). Acting as a selective collector during the flotation technique for segregating oxide minerals. |
Preparation | The synthesis of salicylhydroxamic acid involved a two-step process. In the first step, methyl salicylate was prepared by esterifying salicylic acid with methanol using 28g (0.2 mol) of salicylic acid, 81 ml of methanol, and 8 ml of concentrated sulfuric acid. In the second step, hydroxylamine was coupled with the methyl salicylate. 13.9 g (0.2mol) of hydroxylamine was mixed with 200 ml of 10% sodium hydroxide solution and cooled. To this, 152.3g (0.1mol) of methyl salicylate was added in small portions with vigorous shaking after each addition to ensure complete dissolution. The mixture was allowed to stand for 36 hours, then acidified with 2M sulphuric acid and cooled. The precipitate was filtered, recrystallized from hot water containing a drop of acetic acid, recooled, and filtered. The yield of white precipitate collected and weighed was 14g of salicylhydroxamic acid. Preparation and Characterization of Salicylhydroxamic acid and its Complexes with Iron (III), Cobalt (II) and Manganese (II) |
Purification Methods | Crystallise the hydroxamic acid from acetic acid. [Beilstein 10 H 98.] |
Packing &shipping&Payment
Shipping:by sea or by air
Payment:T/T,western union,moneygram
Packaging Details drum
Port:Tianjin
Lead Time :
Quantity(Kilograms) | 1 - 10000 | >10000 |
Est. Time(days) | 5 | To be negotiated |
Company information
Hebei Mojin Biotechnology Co., Ltd, Our company is a professional in 4'-Methylacetophenone,Levamisole hydrochloride ,N-Methylformamide and other chemical reagents research and development production enterprises. Our business covers more than 30 countries, most of the big customers come from Europe, America and other countries in the world, we can guarantee the quality and price. In recent decades, with the efforts of all employees, we have established many cooperative companies in shandong, henan, guangdong and other places. Our corporate purpose is based on the market, enhance the strength, take the road of scientific and environmental sustainable development, relying on the country. Technology r & d center, increase the investment in r & d, based on the domestic market, expand the international market, manufacturing quality products, sincere service to the society, into a modern, ecological, scientific and technological enterprise world.
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- Since: 2017-12-08
- Address: Building A, Enjoy city, Zhongshan East Road, Shijiazhuang city, Hebei province
13288715578
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