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Thianaphthene NEW
Price | $50 | $1 |
Package | 1KG | 1000KG |
Min. Order: | 1KG |
Supply Ability: | g-kg-tons, free sample is available |
Update Time: | 2023-12-23 |
Product Details
Product Name: Thianaphthene | CAS No.: 95-15-8 |
Min. Order: 1KG | Purity: 99% |
Supply Ability: g-kg-tons, free sample is available | Release date: 2023/12/23 |
Lead time: In stock | Packaging: bottle/drum/bucket/IBC, as request. |
Delivery: By sea, by air, by express | Origin: Manufacturer |
1. Product information
Product Name: | Thianaphthene |
Synonyms: | THIANAPHTHENE;THIONAPHTHENE;2,3-BENZOTHIOPHENE;BZT;BBT;BENZO2,3THIOPHENE;BENZO[B]THIOPHENE;BENZOTHIOPHENE |
CAS: | 95-15-8 |
MF: | C8H6S |
MW: | 134.2 |
EINECS: | 202-395-7 |
Product Categories: | Heterocycle-oher series;Benzothiophenes;Thiophenes & Benzothiophenes;Building Blocks;Chemical Synthesis;Heterocyclic Building Blocks;Benzothiophene;Halogenated;Organoborons;Thiophenes & Benzothiophenes;bc0001 |
Mol File: | 95-15-8.mol |
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Thianaphthene Chemical Properties |
Melting point | 30-33 °C |
Boiling point | 221-222 °C(lit.) |
density | 1.149 g/mL at 25 °C(lit.) |
refractive index | 1.6332 (estimate) |
Fp | >230 °F |
storage temp. | Store below +30°C. |
solubility | 0.13g/l |
form | Crystalline Solid |
pka | 32.4 |
Specific Gravity | 1.149 |
color | White to pink or yellow |
Water Solubility | insoluble |
Merck | 14,9303 |
BRN | 80580 |
InChIKey | FCEHBMOGCRZNNI-UHFFFAOYSA-N |
LogP | 3.120 |
CAS DataBase Reference | 95-15-8(CAS DataBase Reference) |
NIST Chemistry Reference | Benzo[b]thiophene(95-15-8) |
EPA Substance Registry System | Benzo[b]thiophene (95-15-8) |
Safety Information |
Hazard Codes | Xn,Xi,N |
Risk Statements | 22-36/37/38-20/21/22-51/53 |
Safety Statements | 22-24/25-36-26-61 |
RIDADR | UN3077 |
WGK Germany | 3 |
Hazard Note | Irritant |
TSCA | Yes |
HazardClass | 9 |
PackingGroup | III |
HS Code | 29349990 |
Thianaphthene Usage And Synthesis |
Chemical Properties | WHITE TO RED CRYSTALLINE LOW MELTING SOLID |
Uses | Benzo[b]thiophene has application in organic as well as pharmaceutical industry as a component in the synthesis of Raloxifene, a breast cancer therapeutic, or hydrodesulfurization reactions. |
Uses | manufacture of pharmaceuticals, thioindigo. |
Uses | Benzo[b]thiophene is used in the preparation of 2-thianapthenylphenyllithium, via metalation by n-butyllithium. It is used in organic as well as pharmaceutical industry as a component in the synthesis of raloxifene, a breast cancer therapeutic, or hydrodesulfurization reactions. |
Uses | Thianaphthene may be used in the preparation of 2-thianapthenylphenyllithium, via metalation by n-butyllithium. |
Application | Thianaphthene may be used in the preparation of 2-thianapthenylphenyllithium, via metalation by n-butyllithium. Reaction of ethyl diazoacetate with thianaphthene has been reported. |
Definition | ChEBI: 1-benzothiophene is a benzothiophene and a member of 1-benzothiophenes. |
Synthesis Reference(s) | Journal of the American Chemical Society, 69, p. 2008, 1947 DOI: 10.1021/ja01200a053 Tetrahedron, 27, p. 1253, 1971 DOI: 10.1016/S0040-4020(01)90874-9 |
General Description | Reaction of ethyl diazoacetate with thianaphthene has been reported. |
Purification Methods | 1-Benzothiophene has the odour of naphthalene. If the IR spectrum is not very good, then suspend it in a faintly alkaline aqueous solution and steam distil it. Extract the distillate with Et2O, dry the extract (CaCl2), filter, evaporate the solvent and fractionate the residue. The distillate sets solid. The sulfoxide has m 142o, the picrate has m 148-149o (yellow crystals from EtOH) and the styphnate has m 136-137o. [Hansch & Lindwall J Org Chem 10, 381 1945, Meyer & Meyer Chem Ber 52B 1249 1919, Weisgerber & Kruber 53 1551 1920, Iddon & Scrowston Adv Heterocycl Chem 11 177 1970, Beilstein 17/2 V 6.] |
2. Packaging
For powders: normal is 25kgs/Drum or bag, or larger/smaller package as request.
For liquids: normal 25kgs/drum, 180-300kgs/bucket, or IBC, determined by the nature of the product.
Or smaller package 1kg/bottle, 10kgs/bottle as request.
3. Shipping
4. Contact information
For more details, pls contact us freely.
Email address : elin@fdachem.com
Mob: 86 13613820652
WhatsApp/Skype/Wechat/LINE: 86 13613820652
Company Profile Introduction
Henan Fengda Chemical Co., Ltd. is located in the High-tech Development Zone of Henan Province. Specializing in the production and sales of various fine chemical products required for industrial production, including chemical raw materials, organic raw materials, petrochemicals, chemical reagents, solvents, catalysts, and additives, etc.
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- Since: 2023-02-10
- Address: Room 01, 2288 E05, Building 14, East Henan University, Science and Technology Park, 279 Xisanhuan Ro
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