ChemicalBook >>1,2,4-Trifluorobenzene>>1,2,4-Trifluorobenzene(367-23-7)

1,2,4-Trifluorobenzene(367-23-7)

1,2,4-Trifluorobenzene(367-23-7)
Product IdentificationBack to Contents
【Product Name】

1,2,4-Trifluorobenzene
【CAS】

367-23-7
【Formula】

C6H3F3
【Molecular Weight】

132.08000000000001
【EINECS】

206-684-9
【Beilstein/Gmelin】

2042865
【Beilstein Reference】

4-05-00-00638
Physical and Chemical PropertiesBack to Contents
【Appearance】

Clear, colorless liquid.
【Solubility in water】

Insoluble
【Melting Point】

-35
【Boiling Point】

88
【Vapor Pressure】

63 (25 C)
【Density】

1.26 g/cm3
【Partition Coefficient】

2.22
【Heat Of Vaporization】

31.7 kJ/mol
【Vapor Density】

4.55
【Refractive Index】

1.4171 (20 C)
First Aid MeasuresBack to Contents
【Ingestion】

Never give anything by mouth to an unconscious person. Get medical aid immediately. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
【Inhalation】

Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
【Skin】

Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
【Eyes】

Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Handling and StorageBack to Contents
【Storage】

Keep away from heat, sparks, and flame. Keep away from sources of ignition. Store in a cool, dry place. Store in a tightly closed container. Flammables-area.
【Handling】

Ground and bond containers when transferring material. Use spark-proof tools and explosion proof equipment. Do not get in eyes, on skin, or on clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Keep container tightly closed. Avoid contact with heat, sparks and flame. Use with adequate ventilation. Use only in a chemical fume hood. Wash clothing before reuse. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames. Do not breathe vapors.
Hazards IdentificationBack to Contents
【Inhalation】

Causes respiratory tract irritation. Aspiration may lead to pulmonary edema. Vapors may cause dizziness or suffocation. May cause burning sensation in the chest.
【Skin】

Causes skin irritation. May cause cyanosis of the extremities.
【Eyes】

Causes eye irritation. May cause chemical conjunctivitis.
【Ingestion】

May cause gastrointestinal irritation with nausea, vomiting and diarrhea. Ingestion of large amounts may cause CNS depression.
【Hazards】

Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion hazard indoors, outdoors or in sewers.
【EC Risk Phrase】

R 11 36/37/38
【EC Safety Phrase】

S 16 23 26 36
【UN (DOT)】

1993
Exposure Controls/Personal ProtectionBack to Contents
【Personal Protection】

Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.
【Respirators】

A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant a respirator's use.
【Exposure Effects】

Effects may be delayed.
Fire Fighting MeasuresBack to Contents
【Flash Point】

4
【Fire Fighting】

Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Will burn if involved in a fire. Use water spray to keep fire-exposed containers cool. Containers may explode in the heat of a fire. Extinguishing media: Use water spray to cool fire-exposed containers. Water may be ineffective. Do NOT use straight streams of water. In case of fire use water spray, dry chemical, carbon dioxide, or appropriate foam.
【Fire Potential】

HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames.
Accidental Release MeasuresBack to Contents
【Small spills/leaks】

Clean up spills immediately, using the appropriate protective equipment. Cover with sand, dry lime or soda ash and place in a closed container for disposal. Remove all sources of ignition. Use a spark-proof tool. Provide ventilation. A vapor suppressing foam may be used to reduce vapors.
Stability and ReactivityBack to Contents
【Stability】

Stable at room temperature in closed containers under normal storage and handling conditions.
【Incompatibilities】

Strong oxidizing agents.
【Decomposition】

Carbon monoxide, carbon dioxide, hydrogen fluoride.
【Combustion Products】

Fire may produce irritating, corrosive and/or toxic gases.
Transport InformationBack to Contents
【UN Number】

1993
【Hazard Class】

3
【Packing Group】

I; II; III
Company Name: Wuhan EEChem Technologies Co., Ltd
Tel: 0711-3617768 13308685235
Fax: 0711-3616558
WebSite: http://www.eechemistry.com
Company Name: Fluoropharm Co., Ltd.
Tel: 0571-0571-85586753 13336034509
Fax: 0571 85586753
WebSite: http://www.fluoropharm.com
Company Name: Taizhou Jun Rui Import and Export Co., Ltd.
Tel: 0576-88808091 13958565781
Fax: 0576-88808091
WebSite: http://www.groundfortune.com
Company Name: Zhejiang Xieshi New Materials Co., Ltd.,
Tel: 17858121723
Fax:
WebSite: www.xieshichem.com/
Company Name: J & K SCIENTIFIC LTD.
Tel: 010-82848833 400-666-7788
Fax: 86-10-82849933
WebSite: http://www.jkchemical.com
Company Name: Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel: 021-61259108 18621169109
Fax: 86-21-61259102
WebSite: https://www.meryer.com/cn/index/
Company Name: Alfa Aesar
Tel: 400-6106006
Fax: 021-67582001/03/05
WebSite: http://chemicals.thermofisher.cn
Company Name: TCI (Shanghai) Development Co., Ltd.
Tel: 021-67121386
Fax: 021-67121385
WebSite: https://www.tcichemicals.com/CN/zh/