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4-Ethylbenzoyl chloride(16331-45-6)

4-Ethylbenzoyl chloride(16331-45-6)
Product IdentificationBack to Contents
【Product Name】

4-Ethylbenzoyl chloride
【Synonyms】

Benzoyl chloride, 4-ethyl-
【CAS】

16331-45-6
【Formula】

C9H9ClO
【Molecular Weight】

168.62
【EINECS】

240-404-6
【Beilstein/Gmelin】

2206041
【Beilstein Reference】

3-09-00-02431
Physical and Chemical PropertiesBack to Contents
【Appearance】

Pale-yellow liquid.
【Solubility in water】

Insoluble
【Melting Point】

42 - 43
【Boiling Point】

235 - 236
【Vapor Pressure】

0.05 (25 C)
【Density】

1.14 g/cm3
【Partition Coefficient】

3.2
【Heat Of Vaporization】

47.2 kJ/mol
【Vapor Density】

5.81
【Refractive Index】

1.55 (20 C)
First Aid MeasuresBack to Contents
【Ingestion】

Do NOT induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.
【Inhalation】

Get medical aid immediately. Remove from exposure to fresh air immediately. If breathing is difficult, give oxygen. DO NOT use mouth-to-mouth respiration. If breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device such as a bag and a mask.
【Skin】

Get medical aid immediately. Immediately flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Destroy contaminated shoes.
【Eyes】

Get medical aid immediately. Do NOT allow victim to rub or keep eyes closed. Extensive irrigation is required (at least 30 minutes).
Handling and StorageBack to Contents
【Storage】

Store in a cool, dry place. Keep container closed when not in use. Corrosives area. Store protected from moisture.
【Handling】

Keep container tightly closed. Do not get on skin or in eyes. Do not ingest or inhale. Use with adequate ventilation. Do not allow contact with water. Use only in a chemical fume hood. Discard contaminated shoes. Keep from contact with moist air and steam.
Hazards IdentificationBack to Contents
【Ingestion】

May cause severe and permanent damage to the digestive tract. Causes gastrointestinal tract burns. May cause headache. May cause nausea and vomiting.
【Inhalation】

May cause irritation of the respiratory tract with burning pain in the nose and throat, coughing, wheezing, shortness of breath and pulmonary edema. Causes chemical burns to the respiratory tract. Inhalation may be fatal as a result of spasm, inflammation, edema of the larynx and bronchi, chemical pneumonitis and pulmonary edema.
【Skin】

Causes skin burns.
【Eyes】

Causes eye burns. Lachrymator.
【Hazards】

When heated, vapors may form explosive mixtures with air: indoors, outdoors, and sewers explosion hazards.
【EC Risk Phrase】

R 34
【EC Safety Phrase】

S 26 36/37/39 45
【UN (DOT)】

3265
Exposure Controls/Personal ProtectionBack to Contents
【Personal Protection】

Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to minimize contact with skin.
【Respirators】

A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant a respirator's use.
Fire Fighting MeasuresBack to Contents
【Flash Point】

100
【Fire Fighting】

Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Containers may explode when heated. Extinguishing media: Use foam, dry chemical, or carbon dioxide. Do NOT get water inside containers. Cool containers with flooding quantities of water until well after fire is out.
【Fire Potential】

Combustible material: may burn but does not ignite readily.
Accidental Release MeasuresBack to Contents
【Small spills/leaks】

Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container. Clean up spills immediately, using the appropriate protective equipment. Remove all sources of ignition. Provide ventilation. Do not get water inside containers.
Stability and ReactivityBack to Contents
【Incompatibilities】

Moisture, strong bases, strong oxidizing agents.
【Stability】

Stable at room temperature in closed containers under normal storage and handling conditions.
【Decomposition】

Hydrogen chloride, carbon monoxide, irritating and toxic fumes and gases, carbon dioxide.
【Combustion Products】

Fire may produce irritating, corrosive and/or toxic gases.
Transport InformationBack to Contents
【UN Number】

3265
【Hazard Class】

8
【Packing Group】

I; II; III
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