ChemicalBook >>3-Methyl-1-pentyn-3-ol>>3-Methyl-1-pentyn-3-ol(77-75-8)

3-Methyl-1-pentyn-3-ol(77-75-8)

3-Methyl-1-pentyn-3-ol(77-75-8)
Product IdentificationBack to Contents
【Product Name】

3-Methyl-1-pentyn-3-ol
【Synonyms】

2-Ethynyl-2-butanol
3-Methylpent-1-yn-3-ol
Anti-stress
Diethyl bicarbamate
Ethyl hydrazoformate
Ethyl N-(ethoxycarbonylamino)carbamate
Methylparafynol
Methylpentynol
Pentydorm
s-Dicarbethoxyhydrazine
【CAS】

4114-28-7
【CAS】

77-75-8
【Formula】

C6H10O
【Formula】

C6H12N2O4
【Molecular Weight】

98.15
【Molecular Weight】

176.17
【EINECS】

201-055-5
【EINECS】

223-902-8
【RTECS】

SC4900000
【RTECS Class】

Drug
【Merck】

13,5870
【Beilstein/Gmelin】

1781585
【Beilstein/Gmelin】

969340
【Beilstein Reference】

4-01-00-02242
【Beilstein Reference】

4-03-00-00175
【EC Class】

flammable, harmful, dangerous for the environment
Physical and Chemical PropertiesBack to Contents
【Appearance】

Clear slightly yellow liquid.
【Appearance】

White crystalline powder.
【Solubility in water】

Slightly soluble
【Solubility in water】

Soluble
【Melting Point】

-30
【Melting Point】

130 - 131
【Boiling Point】

250
【Boiling Point】

122
【Vapor Pressure】

0.02 (25 C)
【Vapor Pressure】

53 (20 C)
【Density】

0.869 g/cm3 (19 C)
【Density】

1.32 g/cm3
【pKa/pKb】

13.34 (pKa)
【pKa/pKb】

8.81 (pKa)
【Partition Coefficient】

.67
【Heat Of Vaporization】

48.7 kJ/mol
【Vapor Density】

3.38
【Refractive Index】

1.432 (19 C)
First Aid MeasuresBack to Contents
【Ingestion】

Get medical aid. Wash mouth out with water.
【Ingestion】

Never give anything by mouth to an unconscious person. Get medical aid immediately. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
【Inhalation】

Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
【Inhalation】

Get medical aid immediately. Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. DO NOT use mouth-to-mouth respiration.
【Inhalation】

May cause respiratory tract irritation.
【Skin】

May cause skin irritation.
【Skin】

Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes.
【Skin】

Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
【Eyes】

May cause eye irritation.
【Eyes】

Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
【Eyes】

Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Handling and StorageBack to Contents
【Storage】

Keep away from heat, sparks, and flame. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Flammables-area.
【Storage】

Store in a cool, dry place. Store in a tightly closed container.
【Handling】

Wash thoroughly after handling. Use only in a well ventilated area. Ground and bond containers when transferring material. Use spark-proof tools and explosion proof equipment. Avoid contact with eyes, skin, and clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Avoid contact with heat, sparks and flame. Avoid ingestion and inhalation. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames.
【Handling】

Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes.
Hazards IdentificationBack to Contents
【Ingestion】

The toxicological properties of this substance have not been fully investigated.
【Inhalation】

May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated. Aspiration may lead to pulmonary edema. Vapors may cause dizziness or suffocation. May cause burning sensation in the chest.
【Skin】

May cause skin irritation. May cause dermatitis. May cause cyanosis of the extremities.
【Eyes】

May cause eye irritation. May cause chemical conjunctivitis and corneal damage.
【Ingestion】

May cause gastrointestinal irritation with nausea, vomiting and diarrhea. The toxicological properties of this substance have not been fully investigated. Ingestion of large amounts may cause CNS depression.
【Hazards】

Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion hazard indoors, outdoors or in sewers.
【EC Risk Phrase】

R 10 22
【EC Safety Phrase】

S 16 23 36/37
【EC Safety Phrase】

S 22 24/25
【UN (DOT)】

1987
Exposure Controls/Personal ProtectionBack to Contents
【Personal Protection】

Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.
【Personal Protection】

Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to minimize contact with skin.
【Respirators】

Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.
【Respirators】

A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant a respirator's use.
【Exposure Effects】

Effects may be delayed.
【Poison Class】

4
Fire Fighting MeasuresBack to Contents
【Flash Point】

105
【Flash Point】

29
【Autoignition】

350
【Fire Fighting】

Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Will burn if involved in a fire. Use water spray to keep fire-exposed containers cool. Containers may explode in the heat of a fire. To extinguish fire, use water, dry chemical, chemical foam, or alcohol-resistant foam. Use water spray to cool fire-exposed containers. Water may be ineffective. Do NOT use straight streams of water.
【Fire Fighting】

Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. To extinguish fire use water spray, dry chemical, carbon dioxide, or chemical foam.
【Upper exp. limit】

16.0
【Lower exp. limit】

1.8
【Fire Potential】

HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames.
Accidental Release MeasuresBack to Contents
【Small spills/leaks】

Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container. Avoid runoff into storm sewers and ditches which lead to waterways. Remove all sources of ignition. Use a spark-proof tool. Provide ventilation. A vapor suppressing foam may be used to reduce vapors.
【Small spills/leaks】

Vacuum or sweep up material and place into a suitable disposal container.
Stability and ReactivityBack to Contents
【Disposal Code】

1
【Stability】

No data.
【Stability】

Stable under normal temperatures and pressures.
【Incompatibilities】

Strong oxidizing agents, strong acids, strong reducing agents, acid chlorides, acid anhydrides, phosphorus halides.
【Incompatibilities】

Strong oxidizing agents.
【Decomposition】

Carbon monoxide, irritating and toxic fumes and gases, carbon dioxide.
【Decomposition】

Carbon monoxide, oxides of nitrogen, carbon dioxide.
【Combustion Products】

Fire may produce irritating, corrosive and/or toxic gases.
Transport InformationBack to Contents
【UN Number】

1987
【Hazard Class】

3
【Packing Group】

I; II; III
【HS Code】

2905 29 90
【HS Code】

2928 00 90
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