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Silver hexafluorophosphate(26042-63-7)

Silver hexafluorophosphate(26042-63-7)
Product IdentificationBack to Contents
【Product Name】

Silver hexafluorophosphate
【Synonyms】

Phosphate(1-), hexafluoro-, silver(1+)
Silver(1+) hexafluorophosphate(1-)
【CAS】

26042-63-7
【Formula】

AgF6P
【Molecular Weight】

252.83
【EINECS】

247-428-6
【Beilstein/Gmelin】

11384 (G)
Physical and Chemical PropertiesBack to Contents
【Appearance】

Off-white crystalline powder.
【Usage】

Reagent in inorganic and organometallic chemistry.
First Aid MeasuresBack to Contents
【Ingestion】

Do NOT induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.
【Inhalation】

Get medical aid immediately. Remove from exposure to fresh air immediately. If breathing is difficult, give oxygen. DO NOT use mouth-to-mouth respiration. If breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device such as a bag and a mask.
【Skin】

Get medical aid immediately. Immediately flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Destroy contaminated shoes.
【Eyes】

Get medical aid immediately. Do NOT allow victim to rub or keep eyes closed. Extensive irrigation is required (at least 30 minutes).
Handling and StorageBack to Contents
【Storage】

Keep container closed when not in use. Store in a tightly closed container. Corrosives area. Keep away from acids. Store protected from moisture. Store protected from light. Store in a cool, dry area away from incompatible substances.
【Handling】

Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use only in a well ventilated area. Minimize dust generation and accumulation. Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on skin, or on clothing. Keep container tightly closed. Do not ingest or inhale. Store protected from light. Do not allow contact with water. Discard contaminated shoes. Keep from contact with moist air and steam.
Hazards IdentificationBack to Contents
【Inhalation】

May cause severe irritation of the respiratory tract with sore throat, coughing, shortness of breath and delayed lung edema. Causes chemical burns to the respiratory tract. Aspiration may lead to pulmonary edema. May cause systemic effects.
【Skin】

Causes skin burns. May cause skin rash (in milder cases), and cold and clammy skin with cyanosis or pale color.
【Eyes】

Causes eye burns. May cause chemical conjunctivitis and corneal damage.
【Ingestion】

May cause severe and permanent damage to the digestive tract. Causes gastrointestinal tract burns. May cause perforation of the digestive tract. Ingestion of silver compounds may cause abdominal pain, rigidity, convulsions and shock. May cause systemic effects.
【Hazards】

Contact with metals may evolve flammable hydrogen gas.
【UN (DOT)】

1759
Exposure Controls/Personal ProtectionBack to Contents
【Personal Protection】

Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.
【Respirators】

A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant a respirator's use.
【Exposure Effects】

Effects may be delayed. May cause argyria (a slate gray or bluish discoloration of the skin and deep tissues due to the deposit of insoluble albuminate of silver).
Fire Fighting MeasuresBack to Contents
【Fire Fighting】

Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. This material in sufficient quantity and reduced particle size is capable of creating a dust explosion. To extinguish fire, use water, dry chemical, chemical foam, or alcohol-resistant foam. Use agent most appropriate to extinguish fire. Do NOT get water inside containers.
【Fire Potential】

Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes.
Accidental Release MeasuresBack to Contents
【Small spills/leaks】

Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately, using the appropriate protective equipment. Avoid generating dusty conditions. Provide ventilation. Do not get water inside containers.
Stability and ReactivityBack to Contents
【Stability】

Stable under normal temperatures and pressures. May discolor on exposure to light.
【Incompatibilities】

Strong oxidizing agents, acids, moisture, phosphorus pentafluoride.
【Decomposition】

Phosphine, oxides of phosphorus, hydrogen fluoride.
【Combustion Products】

Fire may produce irritating, corrosive and/or toxic gases.
Transport InformationBack to Contents
【UN Number】

1759
【Hazard Class】

8
【Packing Group】

I; II; III
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