| Product Identification | Back to Contents | 【Product Name】
Glycerine | 【Synonyms】
(2R,3R,4R,5R)-2-[6-(benzylamino)purin-9-yl]-5-(hydroxymethyl)oxolane-3,4-diol
1,2,3-Propanetriol
1,2,3-Trihydroxypropane
6-Benzyladenine
6-Benzylamino-9beta-D-ribofuranosylpurine
Glycerin
Glycerol
Glycol alcohol
Propane-1,2,3-triol
Pyranylbenzyladenine | 【CAS】
4294-16-0 | 【CAS】
56-81-5 | 【Formula】
C17H19N5O4 | 【Formula】
C3H8O3 | 【Molecular Weight】
92.09 | 【Molecular Weight】
357.36 | 【EINECS】
200-289-5 | 【EINECS】
224-298-9 | 【RTECS】
MA8050000 | 【RTECS Class】
Drug; Mutagen; Reproductive Effector; Human Data; Primary Irritant | 【Merck】
13,4497 | 【Beilstein/Gmelin】
56815 | 【Beilstein/Gmelin】
635685 | 【Beilstein Reference】
4-01-00-02751 | 【Beilstein Reference】
4-26-00-03682 |
| Physical and Chemical Properties | Back to Contents | 【Appearance】
Clear, colorless, syrupy liquid, odorless, hygroscopic. | 【Appearance】
White crystals. | 【Solubility in water】
Miscible | 【Melting Point】
18 | 【Melting Point】
184 - 186 | 【Boiling Point】
290 | 【Vapor Pressure】
0.0002 (25 C) | 【Density】
1.261 g/cm3 (20 C) | 【Density】
1.48 g/cm3 | 【pKa/pKb】
13.52 (pKa) | 【Partition Coefficient】
-1.76 | 【Partition Coefficient】
2.03 | 【Heat Of Vaporization】
61.4 kJ/mol | 【Heat Of Combustion】
-1663 kJ/mol | 【Usage】
Cosmetics, hand lotions, adjuvant. | 【Usage】
Plant growth regulator. | 【Vapor Density】
3.17 | 【Saturation Concentration】
0.0003% at 50 C | 【Odor threshold】
Odorless | 【Refractive Index】
1.4758 (20 C) |
| First Aid Measures | Back to Contents | 【Ingestion】
Never give anything by mouth to an unconscious person. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water. Get medical aid if irritation or symptoms occur. | 【Ingestion】
Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water. | 【Inhalation】
Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid if cough or other symptoms appear. | 【Inhalation】
Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. | 【Inhalation】
May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated. | 【Skin】
May cause skin irritation. | 【Skin】
Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Get medical aid if irritation develops or persists. Wash clothing before reuse. | 【Skin】
Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. | 【Eyes】
May cause eye irritation. | 【Eyes】
Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. | 【Eyes】
Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. If irritation develops, get medical aid. |
| Handling and Storage | Back to Contents | 【Storage】
Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Deep freeze (below -20 C). | 【Storage】
Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. No special precautions indicated. | 【Handling】
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Minimize dust generation and accumulation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. | 【Handling】
Wash thoroughly after handling. Wash hands before eating. Use with adequate ventilation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Wash clothing before reuse. |
| Hazards Identification | Back to Contents | 【Ingestion】
May cause irritation of the digestive tract. The toxicological properties of this substance have not been fully investigated. | 【Inhalation】
Low hazard for usual industrial handling. Inhalation of a mist of this material may cause respiratory tract irritation. | 【Skin】
May cause skin irritation. Low hazard for usual industrial handling. | 【Eyes】
May cause eye irritation. | 【Ingestion】
Ingestion of large amounts may cause gastrointestinal irritation. Low hazard for usual industrial handling. May cause headache. | 【EC Safety Phrase】
S 28A 37 45 |
| Exposure Controls/Personal Protection | Back to Contents | 【Personal Protection】
Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to minimize contact with skin. | 【Personal Protection】
Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. | 【Respirators】
Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary. | 【Respirators】
A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant a respirator's use. | 【Exposure Effects】
Repeated exposure may result in injury of the kidneys. | 【Exposure limit(s)】
NIOSH REL: See Appendix D OSHA PEL: TWA 15 mg/m3 (total) TWA 5 mg/m3 (resp) | 【Poison Class】
- |
| Fire Fighting Measures | Back to Contents | 【Flash Point】
199 | 【Autoignition】
370 | 【Fire Fighting】
Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Containers may explode when heated. Extinguishing media: Use water spray to cool fire-exposed containers. Use agent most appropriate to extinguish fire. In case of fire use water spray, dry chemical, carbon dioxide, or appropriate foam. | 【Fire Fighting】
Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Extinguishing media: Use agent most appropriate to extinguish fire. In case of fire use water spray, dry chemical, carbon dioxide, or appropriate foam. | 【Upper exp. limit】
19 | 【Lower exp. limit】
2.7 | 【Fire Potential】
This chemical is combustible. |
| Accidental Release Measures | Back to Contents | 【Small spills/leaks】
Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container. Avoid runoff into storm sewers and ditches which lead to waterways. Clean up spills immediately, using the appropriate protective equipment. Remove all sources of ignition. Provide ventilation. | 【Small spills/leaks】
Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately, using the appropriate protective equipment. Avoid generating dusty conditions. Provide ventilation. |
| Stability and Reactivity | Back to Contents | 【Disposal Code】
1 | 【Incompatibilities】
Incompatible with strong oxidizers Incompatible with hydrogen peroxide, potassium permanganate, nitric acid + sulfuric acid, perchloric acid + lead oxide, acetic anhydride, aniline + nitrobenzene, Ca(OCl)2, CrO3, F2 + PbO, KMnO4, K2O2, AgClO4 and NaH Reacts with acetic acid, potassium peroxide, sodium peroxide, hydrochloric acid, (HClO4 + PbO) and Na2O2 Reacts with ethylene oxide, perchloric acid, nitric acid + hydrofluoric acid and phosphorus triiodide. | 【Incompatibilities】
Oxidizing agents. | 【Stability】
Stable under normal shipping and handling conditions. | 【Stability】
Stable under normal temperatures and pressures. | 【Decomposition】
Nitrogen oxides, carbon monoxide, irritating and toxic fumes and gases, carbon dioxide. | 【Decomposition】
Carbon monoxide, irritating and toxic fumes and gases, carbon dioxide. |
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