ChemicalBook >>Bromodiphenylmethane>>Diphenylbromomethane(776-74-9)

Diphenylbromomethane(776-74-9)

Diphenylbromomethane(776-74-9)
Product IdentificationBack to Contents
【Product Name】

Diphenylbromomethane
【Synonyms】

(bromo-phenylmethyl)benzene
Bromo(diphenyl)methane
Bromodiphenylmethane
【CAS】

776-74-9
【Formula】

C13H11Br
【Molecular Weight】

247.14
【EINECS】

212-279-8
【RTECS】

PA5350000
【Beilstein/Gmelin】

638544
【Beilstein Reference】

4-05-00-01850
【EC Class】

corrosive
Physical and Chemical PropertiesBack to Contents
【Appearance】

Tan, crystalline powder.
【Solubility in water】

450 mg/L
【Melting Point】

36 - 39
【Boiling Point】

315
【Vapor Pressure】

0.00082 (25 C)
【Density】

1.491 g/cm3 (13 C)
【Partition Coefficient】

4.64
【Heat Of Vaporization】

53.4 kJ/mol
【Refractive Index】

1.6197
First Aid MeasuresBack to Contents
【Ingestion】

Never give anything by mouth to an unconscious person. Get medical aid immediately. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
【Inhalation】

Get medical aid immediately. Remove from exposure to fresh air immediately. If breathing is difficult, give oxygen. DO NOT use mouth-to-mouth respiration. If breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device such as a bag and a mask.
【Skin】

Get medical aid immediately. Immediately flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Destroy contaminated shoes.
【Eyes】

Get medical aid immediately. Do NOT allow victim to rub or keep eyes closed. Extensive irrigation is required (at least 30 minutes).
Handling and StorageBack to Contents
【Storage】

Keep container closed when not in use. Corrosives area.
【Handling】

Use only in a well ventilated area. Minimize dust generation and accumulation. Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on skin, or on clothing. Keep container tightly closed. Do not ingest or inhale. Discard contaminated shoes.
Hazards IdentificationBack to Contents
【Inhalation】

May cause liver and kidney damage. Causes chemical burns to the respiratory tract. Aspiration may lead to pulmonary edema. May cause cardiac abnormalities. May cause systemic effects.
【Skin】

Causes skin irritation and burns. May cause skin rash (in milder cases), and cold and clammy skin with cyanosis or pale color.
【Eyes】

Causes eye irritation and burns. May cause chemical conjunctivitis and corneal damage.
【Ingestion】

May cause severe and permanent damage to the digestive tract. May cause liver and kidney damage. May cause perforation of the digestive tract. May cause cardiac disturbances. May cause central nervous system effects. May cause systemic effects.
【Hazards】

When heated, vapors may form explosive mixtures with air: indoors, outdoors, and sewers explosion hazards. May polymerize explosively when heated or involved in a fire. Contact with metals may evolve flammable hydrogen gas. Containers may explode when heated. Runoff may pollute waterways. Substance may be transported in a molten form.
【EC Risk Phrase】

R 34 36/37
【EC Safety Phrase】

S 26 36/37/39 45
【UN (DOT)】

1770
Exposure Controls/Personal ProtectionBack to Contents
【Personal Protection】

Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.
【Respirators】

Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.
【Exposure Effects】

May cause liver and kidney damage. Effects may be delayed.
Fire Fighting MeasuresBack to Contents
【Flash Point】

138
【Fire Fighting】

Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Contact with metals may evolve flammable hydrogen gas. Contact with water forms corrosive vapors. Extinguishing media: DO NOT USE WATER! Cool containers with flooding quantities of water until well after fire is out. Use dry chemical, carbon dioxide, or appropriate foam.
【Fire Potential】

May burn but does not ignite readily.
Accidental Release MeasuresBack to Contents
【Small spills/leaks】

Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately, using the appropriate protective equipment. Avoid generating dusty conditions. Provide ventilation.
Stability and ReactivityBack to Contents
【Disposal Code】

3
【Incompatibilities】

Oxidizing agents, bases, alcohols, amines, steel, moisture.
【Stability】

Stable under normal temperatures and pressures.
【Decomposition】

Carbon monoxide, irritating and toxic fumes and gases, carbon dioxide, hydrogen bromide.
【Combustion Products】

During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion.
Transport InformationBack to Contents
【UN Number】

1770
【Hazard Class】

8
【Packing Group】

II
【HS Code】

2903 69 90
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