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1,3-Diaminopropane(109-76-2)

1,3-Diaminopropane(109-76-2)
Product IdentificationBack to Contents
【Product Name】

1,3-Diaminopropane
【Synonyms】

1,3-Diaminopropane
Trimethylenediamine
【CAS】

109-76-2
【Formula】

C3H10N2
【Molecular Weight】

74.13
【EINECS】

203-702-7
【RTECS】

TX6825000
【RTECS Class】

Reproductive Effector; Primary Irritant
【Beilstein/Gmelin】

605277
【Beilstein Reference】

4-04-00-01258
【EC Class】

flammable, toxic, corrosive
Physical and Chemical PropertiesBack to Contents
【Appearance】

Colorless liquid with a strong amine odor
【Solubility in water】

Soluble
【Melting Point】

-12
【Boiling Point】

140
【Vapor Pressure】

88 (80 C)
【Density】

0.863 g/cm3 (20 C)
【pKa/pKb】

10.94(at 10℃) (pKa)
【Partition Coefficient】

-1.45
【Heat Of Vaporization】

43.33 kJ/mol
【Vapor Density】

2.5
【Refractive Index】

1.441 (20 C)
First Aid MeasuresBack to Contents
【Ingestion】

Never give anything by mouth to an unconscious person. Get medical aid immediately. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
【Inhalation】

Get medical aid immediately. Remove from exposure to fresh air immediately. If breathing is difficult, give oxygen. DO NOT use mouth-to-mouth respiration. If breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device such as a bag and a mask.
【Skin】

Get medical aid immediately. Immediately flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Destroy contaminated shoes.
【Eyes】

Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately. Do NOT allow victim to rub or keep eyes closed. Extensive irrigation is required (at least 30 minutes).
Handling and StorageBack to Contents
【Storage】

Keep away from heat, sparks, and flame. Keep away from sources of ignition. Keep container closed when not in use. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Flammables-area. Store protected from moisture.
【Handling】

Ground and bond containers when transferring material. Use spark-proof tools and explosion proof equipment. Do not get in eyes, on skin, or on clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Keep container tightly closed. Avoid contact with heat, sparks and flame. Do not ingest or inhale. Use only in a chemical fume hood. Discard contaminated shoes. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames. Do not breathe vapors.
Hazards IdentificationBack to Contents
【Inhalation】

May cause severe irritation of the respiratory tract with sore throat, coughing, shortness of breath and delayed lung edema. Causes chemical burns to the respiratory tract. Vapors may cause dizziness or suffocation.
【Skin】

May be fatal if absorbed through the skin. Causes skin burns. Toxic in contact with skin.
【Eyes】

Causes eye burns. Causes redness and pain.
【Ingestion】

Harmful if swallowed. May cause severe and permanent damage to the digestive tract. Causes gastrointestinal tract burns.
【Hazards】

This compound is a flammable liquid.
【EC Risk Phrase】

R 10 22 24 35
【EC Safety Phrase】

S 26 36/37/39 45
【UN (DOT)】

2734
Exposure Controls/Personal ProtectionBack to Contents
【Personal Protection】

Eyes: Wear safety glasses and chemical goggles if splashing is possible. Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to minimize contact with skin.
【Respirators】

A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant a respirator's use. Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.
【Exposure Effects】

May cause reproductive and fetal effects.
【Poison Class】

3
Fire Fighting MeasuresBack to Contents
【Flash Point】

50
【Autoignition】

350
【Fire Fighting】

Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Combustion generates toxic fumes. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Will burn if involved in a fire. Use water spray to keep fire-exposed containers cool. Containers may explode in the heat of a fire. Extinguishing media: For small fires, use dry chemical, carbon dioxide, water spray or alcohol-resistant foam. For large fires, use water spray, fog, or alcohol-resistant foam. Use water spray to cool fire-exposed containers. Use foam, dry chemical, or carbon dioxide. Water may be ineffective. If water is the only media available, use in flooding amounts.
【Upper exp. limit】

15.2
【Lower exp. limit】

2.8
【Fire Potential】

Flammable/combustible material. May be ignited by heat, sparks or flames.
Accidental Release MeasuresBack to Contents
【Small spills/leaks】

Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container. Clean up spills immediately, using the appropriate protective equipment. Remove all sources of ignition. Use a spark-proof tool. Provide ventilation. A vapor suppressing foam may be used to reduce vapors.
Stability and ReactivityBack to Contents
【Disposal Code】

5
【Stability】

Stable.
【Incompatibilities】

Strong oxidizing agents, acids, carbon dioxide, acid anhydrides, acid chlorides, moisture.
【Decomposition】

Nitrogen oxides, carbon monoxide, carbon dioxide.
【Combustion Products】

Fire will produce irritating, corrosive and/or toxic gases.
Transport InformationBack to Contents
【UN Number】

2734
【Hazard Class】

8
【Packing Group】

I; II
【HS Code】

2921 29 00
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