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alpha-Methylbenzyl bromide(585-71-7)

alpha-Methylbenzyl bromide(585-71-7)
Product IdentificationBack to Contents
【Product Name】

alpha-Methylbenzyl bromide
【Synonyms】

(alpha-Bromoethyl)benzene
1-Bromo-1-phenylethane
1-Phenethyl bromide
1-Phenyl-1-nromoethane
alpha-Methylbenzyl bromide
alpha-Phenethyl bromide
【CAS】

585-71-7
【Formula】

C8H9Br
【Molecular Weight】

185.06
【EINECS】

209-560-2
【Beilstein/Gmelin】

507210
【Beilstein Reference】

2-05-00-00278
Physical and Chemical PropertiesBack to Contents
【Appearance】

Clear, yellow to brown liquid.
【Solubility in water】

Insoluble
【Melting Point】

50
【Boiling Point】

203
【Vapor Pressure】

0.4 (25 C)
【Density】

1.3605 g/cm3 (20 C)
【Partition Coefficient】

3.27
【Heat Of Vaporization】

42.1 kJ/mol
【Vapor Density】

6.4
【Refractive Index】

1.5619 (20 C)
First Aid MeasuresBack to Contents
【Ingestion】

Do NOT induce vomiting. Allow the victim to rinse his mouth and then to drink 2-4 cupfuls of water, and seek medical advice.
【Inhalation】

Move patient to fresh air. Monitor for respiratory distress. If cough or difficulty breathing develops, evaluate for respiratory tract irritation, bronchitis, or pneumonitis. Administer oxygen and assist ventilation as required. Treat bronchospasm with beta2 agonist and corticosteroid aerosols.
【Skin】

Remove contaminated clothing and wash exposed area thoroughly with soap and water. A physician should examine the area if irritation or pain persists. Remove all contaminated clothing while avoiding self-contamination. Meticulously wash all exposed areas with copious amounts of soap and water. The patient's clothing may contain residual particles from the exposure and clothing should be removed and stored in a sealed polythene bag to prevent degassing. If clothing is to be washed, cold water should be used because hot wat will cause residual o-chlorobenzylidene malononitrile (cs) gas to vaporize.
【Eyes】

Irrigate exposed eyes with copious amounts of tepid water for at least 15 minutes. If irritation, pain, swelling, lacrimation, or photophobia persist, the patient should be seen in a health care facility.
Handling and StorageBack to Contents
【Storage】

Store in a cool, dry place. Keep container closed when not in use.
【Handling】

All chemicals should be considered hazardous. Avoid direct physical contact. Use appropriate, approved safety equipment. Untrained individuals should not handle this chemical or its container. Handling should occur in a chemical fume hood.
Hazards IdentificationBack to Contents
【Inhalation】

Cough, rhinorrhea, sneezing, chest tightness, and laryngospasm may occur shortly following exposure due to the irritant effects.
【Skin】

Irritation may occur to all body surfaces where significant exposure has occurred. Painful contact dermatitis may persist for several hours following exposure to mace containing capsaicin. Bullous dermatitis may develop 12 to three days after exposure to tear gas containing o-chlorobenzylidene malononitrile (cs). Erythema, vesicle eruptions, and denuded areas with weeping tender erythematous base may develop one day after exposure to mace containing 1-chloroacetophenone (cn).
【Ingestion】

A metallic taste with a burning sensation of the tongue is common. Nausea is common; vomiting occurs occasionally. Epigastric discomfort and burping may occur if tear gas is swallowed.
【EC Risk Phrase】

R 34
【EC Safety Phrase】

S 26 36/37/39 45
【UN (DOT)】

3265
Exposure Controls/Personal ProtectionBack to Contents
【Personal Protection】

Wear safety goggles and appropriate protective gloves and clothing.
【Respirators】

Wear a NIOSH/MSHA or European Standard EN 149 approved full-facepiece airline respirator in the positive pressure mode with emergency escape provisions.
【Exposure Effects】

Agitation and syncope, both attributed to panic, have been reported.
Fire Fighting MeasuresBack to Contents
【Flash Point】

81
【Fire Fighting】

Wear a self-contained breathing apparatus inpressure-demand, MSHA/NIOSH (approved or equivalent), and fullprotective gear. During a fire, irritating and highly toxic gasesmay be generated by thermal decomposition or combustion. In case of fire, use water, dry chemical, chemical foam, oralcohol-resistant foam.
【Fire Potential】

Moderate fire hazard, when exposed to heat or flame.
Accidental Release MeasuresBack to Contents
【Small spills/leaks】

Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container. Clean up spills immediately, using the appropriate protective equipment.
Stability and ReactivityBack to Contents
【Stability】

Stable under normal temperatures and pressures.
【Incompatibilities】

Strong oxidizing agents, strong bases.
【Decomposition】

Carbon monoxide, irritating and toxic fumes and gases, carbon dioxide, hydrogen bromide.
Transport InformationBack to Contents
【UN Number】

3265
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