7242-92-4

外-2-氨基降冰片烷(7242-92-4)Raman光谱

产品名称:外-2-氨基降冰片烷

CAS:7242-92-4

分子式:C7H13N

分子量: 111.18

InChI:InChI=1/C7H13N/c8-7-4-5-1-2-6(7)3-5/h5-7H,1-4,8H2/t5-,6+,7+/s3

InChIKey: JEPPYVOSGKWVSJ-QXWMLGDLNA-N

Smiles:[C@]12([H])C[C@]([H])(CC1)C[C@H]2N |&1:0,3,8,r|

Mass

MS-NW-5766          
exo-2-aminonorbornane
C7H13N              (Mass of molecular ion:    111)

   Source Temperature: 250 °C
   Sample Temperature: 190 °C
   Reservoir, 75 eV

      15.0       3.3
      18.0       9.6
      26.0       1.5
      27.0      12.3
      28.0      25.9
      29.0       5.5
      30.0      59.5
      31.0       1.3
      38.0       2.0
      39.0      19.0
      40.0       3.9
      41.0      20.6
      42.0      16.9
      43.0      70.9
      44.0      16.3
      45.0      29.9
      50.0       1.6
      51.0       3.0
      52.0       2.0
      53.0       6.4
      54.0       6.2
      55.0       5.0
      56.0      77.2
      57.0      23.6
      58.0       1.1
      65.0       5.5
      66.0      22.1
      67.0      22.5
      68.0       6.2
      69.0      16.0
      70.0      35.5
      71.0       2.2
      77.0       4.5
      78.0       1.7
      79.0      38.5
      80.0       5.9
      81.0       3.5
      82.0     100.0
      83.0      21.1
      84.0       1.9
      91.0       2.3
      93.0       4.8
      94.0      40.5
      95.0       4.9
      96.0       9.6
      97.0       1.0
     110.0      12.1
     111.0      57.6
     112.0       4.9

400 MHz in CDCl3

¹H NMR	399.65 MHz
C₇ H₁₃ N	0.05 ml : 0.5 ml CDCl₃
exo-2-aminonorbornane

    Assign.     Shift(ppm)

      A             2.805
      B             2.207
      C             1.925
      D             1.633
      E          1.46 to 1.42
      F             1.09
      G             1.06
      J             1.05
      K             1.01
     
     ASSIGNED BY C-H COSY

     Hz     ppm     Int.

   1126.59   2.819    323
   1123.29   2.811    333
   1119.02   2.800    345
   1115.72   2.792    339
    882.20   2.208    502
    771.12   1.930    521
    767.46   1.921    488
    664.43   1.663    277
    661.99   1.657    280
    656.74   1.644    276
    654.30   1.638    289
    651.73   1.631    320
    649.29   1.625    319
    644.04   1.612    310
    641.72   1.606    309
    591.43   1.480    432
    589.72   1.476    575
    587.77   1.471    539
    585.94   1.467    565
    583.50   1.461    411
    581.54   1.456    767
    579.71   1.451    910
    578.25   1.447   1000
    576.05   1.442    717
    574.34   1.438    923
    570.19   1.427    645
    566.77   1.419    483
    565.55   1.416    508
    562.74   1.409    417
    444.34   1.112    474
    442.99   1.109    540
    441.89   1.106    586
    440.67   1.103    474
    434.45   1.088    409
    433.11   1.084    586
    432.01   1.081    748
    430.66   1.078    590
    423.83   1.061    791
    421.88   1.056    739
    416.87   1.044    571
    414.79   1.038    572
    405.03   1.014    377

in CDCl3