别名
(11aS)-(-)-10,11,12,13-四氢茚并[7,1-de:1′, 7′-fg][1,3,2]二氧磷-5-双[(R)-1-苯乙基]胺,N-二[(R)-1-苯乙基]-[(S)-1,1′-螺二氢茚-7,7′-二基]亚磷酰胺
应用
(S)-SIPHOS-PE is a chiral spiro phosphoramidate ligand that can be used to synthesize: Spiroindolenines by Pd-catalyzed intramolecular dearomative arylation of haloaryl-3-substituted indoles. Enantioselective conjugate addition compound by Cu-catalyzed 1,4-addition of diethylzinc (Et2Zn) to cyclic enones. Octaketide natural products via rhodium-phosphoramidite catalyzed alkene hydroacylation.
Sigma-Aldrich西格玛奥德里奇(上海)贸易有限公司
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