一般描述
2-(Trimethylsilyl)-2-cyclohexen-1-one is a silyl enone.
应用
The following silyl enone can be converted into a highly useful cyclohexyne precursor as reported by the Garg and DuBois groups. The resulting silyltriflate adduct can be subjected to various dienes and dipolarophiles in the presence of Cesium Fluoride.
其他说明
Cycloadditions of Cyclohexynes and Cyclopentyne Modular synthesis of the pentacyclic core of batrachotoxin and select batrachotoxin analogue designs
Sigma-Aldrich西格玛奥德里奇(上海)贸易有限公司
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