别名
(S)-2-(2-(二苯基膦)苯基)-4-异丙基-5,5-二甲基-4,5-二氢噁唑,(S)-5,5-(二甲基)-i-Pr-PHOX
应用
Use of 5,5-(Dimethyl)-i-Pr-PHOX as a Practical Equivalent to t-Bu-PHOX in Asymmetric CatalysisDesign, Synthesis, and Applications of Potential Substitutes of t-Bu-Phosphinooxazoline in Pd-Catalyzed Asymmetric Transformations and Their Use for the Improvement of the Enantioselectivity in the Pd-Catalyzed Allylation Reaction of Fluorinated Allyl Enol Carbonates (S)-5,5-(Dimethyl)-i-Pr-PHOX is a phosphinooxazoline ligand (PHOX), belongs to the class of non-C2 symmetric chiral ligand. It can be used in: The enantioselective Pd-catalyzed allylation reactions. The synthesis of (R)-2-phenyl-2,5-dihydrofuran by the enantioselective Heck reaction between 2,3-dihydrofuran and phenyl triflate. The allylation reaction of fluorinated allyl enol carbonates and fluorinated silyl enol ethers to prepare allylated tert α-fluoroketones.
Sigma-Aldrich西格玛奥德里奇(上海)贸易有限公司
联系商家时请提及chemicalbook,有助于交易顺利完成!