中文名:4-氟苯乙炔
英文名:4-Fluorophenylacetylene
中文别名:1-乙炔基-4-氟苯
英文别名:1-Ethynyl-4-fluorobenzene, 99% | CS-W016580 | SCHEMBL186243 | AKOS008901264 | AMY19915 | EN300-103797 | SW219698-1 | F0001-1953 | 4'-Fluorophenylacetylene | 4-Fluorophenylacetylene | 1-Fluoro-4-ethynylbenzene; | PB43440 | 1-Ethynyl-4-fluorobenzene | 1-eth
纯度:98%
货号:E115545
包装:1g、25g、5g
Cas号:766-98-3
存储温度:2-8°C储存,充氩
产品介绍:
1-Ethynyl-4-fluorobenzene (pFAB) is a fluorobenzene derivative. Trianionic pincer alkylidyne complex catalyzed polymerization of 1-ethynyl-4-fluorobenzene has been reported.The surface of the iodophenyl-terminated organic monolayers has been modified by Sonogashira coupling of the iodophenyl groups found on the surface with pFAB. Dimerization catalyzed by Y[N(TMS)2]3 and 4-chloroaniline gave exclusive formation of one of three possible enediynes in excellent yield1-Ethynyl-4-fluorobenzene may be used in the synthesis of the following: · 3-(4-Fluorophenyl)-1H-isochromen-1-one by reacting with 2-iodobenzoic acid in the presence of copper catalyst. · 4-Bromo-3,5-difluoro-2,6-bis-(4-fluoro-phenylethynyl)-pyridine by reacting with 2,4,6-tribromo-3,5-difluoropyridine by palladium catalyzed Sonogashira reaction. · 1-(4-Fluorophenyl)-3-methoxy-3-(4-methoxyphenyl)propan-1-one by reacting with p-anisaldehyde. · 5-(4-Fluorophenyl)-1-(2-nitrobenzyl)-1H-1,2,3-triazole by reacting with 1-(bromomethyl)-2-nitrobenzene in the presence of sodium azide. 1-Ethynyl-4-fluorobenzene, a substituted phenylacetylene, may be used in the synthesis of aryl acetylenes, via Sonogashira type cross coupling reaction with various haloarenes in the presence of bis(μ-iodo)bis((-)-sparteine)dicopper(I) catalyst
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关键字: 1-乙炔基-4-氟苯;1-Ethynyl-4-fluorobenzene, 99% ; CS-W016580 ; SCHEMBL186243
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