中文名:(溴二氟甲基)三甲基硅烷
英文名:(Bromodifluoromethyl)trimethylsilane
中文别名:溴二氟(三甲基硅基)甲烷
英文别名:115262-01-6|(bromodifluoromethyl)trimethylsilane|TriMethyl(broModifluoroMethyl)silane|Silane, (bromodifluoromethyl)trimethyl-|[bromo(difluoro)methyl]-trimethylsilane|[Bromo(difluoro)methyl]trimethylsilane|MFCD18641931|[bromo(difluoro)methyl](trimethyl)sil
纯度:>98.0%(GC)
货号:B152721
包装:1g、5g、25g
Cas号:115262-01-6
存储温度:-20°C储存,充氩
产品介绍:
(Bromodifluoromethyl)trimethylsilane (TMSCF2Br) is commonly used as a source to generate dilfluorocarbene. TMSCF3 (Ruppert-Prakash reagent) and BBr3undergoes fast halogen-exchange reaction to form MSCF2Br.(Bromodifluoromethyl)trimethylsilane may be used in the preparation of: · gem-difluorocyclopropa(e)nes · O-, S-, N-, and P-difluoromethylated compounds · (chlorodifluoromethyl)trimethylsilane As reported by Hu and co-workers, (Bromodifluoromethyl)trimethylsilane is a highly useful reagent for the formation of difluoromethene-containing 3-membered rings and can also difluoromethylate heteroatoms with the assistance of alkaline bases, most effectively KOH.
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