中文名:(叔丁基二甲基硅烷基)乙炔
英文名:(tert-Butyldimethylsilyl)acetylene
中文别名:叔丁基乙炔基二甲基硅烷
英文别名:86318-61-8|(tert-Butyldimethylsilyl)acetylene|TERT-BUTYLDIMETHYLSILYLACETYLENE|ethynyl-t-butyldimethylsilane|TERT-BUTYL(ETHYNYL)DIMETHYLSILANE|tert-butyl-ethynyl-dimethylsilane|tert-butyl-ethynyl-dimethyl-silane|(tert-Butyldimethylsilyl)ethyne|Silane, (1,
纯度:>95.0%(GC)
货号:T162479
包装:25g、5g、1g
Cas号:86318-61-8
存储温度:充氩
产品介绍:
(tert-Butyldimethylsilyl)acetylene is a bulky trialkylsilyl-protected alkyne. It participates in Cadiot-Chodkiewicz cross-coupling reaction with various bromoalkynes to afford synthetically useful unsymmetrical diynes. (tert-Butyldimethylsilyl)acetylene readily undergoes cross-dimerization reaction with various internal phenyl acetylenes in the presence of rhodium dimers and bidentate phosphine ligands to afford enynes.(tert-Butyldimethylsilyl)acetylene may be used in the synthesis of β-alkynylketone[1] and β-alkynyl aldehydes.
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