中文名:氯(1-叔丁基茚基)钯(II)二聚体
英文名:Chloro(1-t-butylindenyl)palladium(II) dimer
中文别名:Umicore CX200;(Pd tBu-Ind Cl)2, Hazari Pd catalyst dimer, Palladium(p-tert-butylindenyl) chloride dimer, [(η3-1-tert-Butylindenyl)(μ-Cl)Pd]2, CX200
英文别名:Umicore CX200;(Pd tBu-Ind Cl)2, Hazari Pd catalyst dimer, Palladium(p-tert-butylindenyl) chloride dimer, [(η3-1-tert-Butylindenyl)(μ-Cl)Pd]2, CX200
纯度:98%
货号:C282882
包装:100mg、500mg
Cas号:1779569-01-5
存储温度:室温
产品介绍:
Application
The following palladium dimer is a precatalyst scaffold for cross-coupling reactions originally reported by the Hazari research group. When used with an selected ligand, the precatalyst exhibits superior activity over a wide array of cross-coupling reactions and under a variety of conditions.
Product class
M-C, Homogeneous Catalysts, Hazari Catalyst, Indenyl Ligands
Reaction type
Cross Coupling Reactions with Arenes, Amination, Buchwald-Hartwig Aminaton, Suzuki-Miyaura Coupling Reaction
Chemical properties
Theoretical metal content
Applications & references
Suzuki-Miyaura coupling reaction catalyzed by an in situ generated solution of [Pd(cinnamyl)Cl]2 and IPr and an in situ generated solution of our Pd-cat. and IPr.
![](https://pmc.umicore.com/api/fw/file/53eb8df2be604c89ae9d2d906c39888117777c80)
Reference: ACS Catal. 2015, 5, 3680 (DOI: 10.1021/acscatal.5b00878)
Suzuki-Miyaura coupling reaction of 2-chloro-4,6-dimethoxyprimidine and benzofuran-2-boronic acid catalyzed by an in situ precatalyst generated from our Pd-cat. and XPhos.
![](https://pmc.umicore.com/api/fw/file/1721848b6ba39515e20b04502f7169f0dbcfb5c5)
Reference: ACS Catal. 2015, 5, 3680 (DOI: 10.1021/acscatal.5b00878)
Suzuki-Miyaura coupling reaction of 2-chloro-1H-benzimidazole and 3-thiophene boronic acid catalyzed by an in situ precatalyst generated from Umicore our Pd-cat. and SPhos.
![](https://pmc.umicore.com/api/fw/file/799306d8cec90cf2b4e046b4deb7eec367c205cd)
Reference: ACS Catal. 2015, 5, 3680 (DOI: 10.1021/acscatal.5b00878)
Suzuki-Miyaura coupling reaction of 2-methoxy chlorobenzene and morpholine catalyzed by an in situ precatalyst generated from our Pd-cat. and RuPhos.
![](https://pmc.umicore.com/api/fw/file/6ef97c3c947641f65ec484ba729d11e2d72c92fd)
Reference: ACS Catal. 2015, 5, 3680 (DOI: 10.1021/acscatal.5b00878)
Suzuki-Miyaura coupling reaction of 3-acetylpyridine and 3-chloropyridine catalyzed by an in situ precatalyst generated from our Pd-cat. and XPhos.
![](https://pmc.umicore.com/api/fw/file/030030910e915e503afec0d008947b5c62429a6b)
Reference: ACS Catal. 2015, 5, 3680 (DOI: 10.1021/acscatal.5b00878)
Suzuki-Miyaura coupling reaction of 4-chloroanisole and potassium isopropyltrifluoroboronate catalyzed by an in situ precatalyst generated from our Pd-cat. and P(tBu)3.
![](https://pmc.umicore.com/api/fw/file/ad0507e9d64916da7ce477d2d7ea4b45b259e473)
Reference: ACS Catal. 2015, 5, 3680 (DOI: 10.1021/acscatal.5b00878)
Hiyama-Denmark Reactions of 4-(trifluoromethyl)chlorobenzene and 4-(methoxy)phenyl silanolate catalyzed by in situ precatalysts generated from our Pd-cat. and different ligands.
![](https://pmc.umicore.com/api/fw/file/b3c38ec5c2ef8463470de5efb9aa22e6506f335d)
Reference: Org. Lett. 2016, 18, 5784 (DOI: 10.1021/acs.orglett.6b02330)
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关键字: Umicore CX200;(Pd tBu-Ind Cl)2, Hazari Pd catalyst dimer, Palladium(p-tert-butylindenyl) chloride dimer, [(η3-1-tert-Butylindenyl)(μ-Cl)Pd]2, CX200;Umicore CX200;(Pd tBu-Ind Cl)2, Hazari Pd catalyst dimer, Palladium(p-tert-butylindenyl) chloride dimer, [(η3-1-tert-Butylindenyl)(μ-Cl)Pd]2, CX200
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