9-Borabicyclo[3.3.1]nonane
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- $45 - $7249.94
- Product name: 9-Borabicyclo[3.3.1]nonane
- CAS: 280-64-8
- MF: C8H15B
- MW: 122.02
- EINECS:206-000-9
- MDL Number:MFCD00074742
- Synonyms:9-BORABICYCLO(3.3.1)NONANE SOLUTION, ~0. 5 M IN THF;9-Borabicyclo[3.3.1]nonane, 0.5M solution in THF;9-BBN,9-BORABICYCLO[3.3.1]NONANE;9-BORABICYCLO[3.3.1]NONANE (9BBN);9-BBN(0.5M in toluene);9-Borabicyclo[3.3.1]nonane0.5M solution in THFAcroSeal§3;1,5-(Boranediyl)cyclooctane;9-Borabicyclo[3.3.1]nonane, 0.5M solution inHexane
15 prices
Selected condition:
Brand
- Alfa Aesar
- American Custom Chemicals Corporation
- Biosynth Carbosynth
- Sigma-Aldrich
- TRC
Package
- 50ml
- 100g
- 4x25ml
- 100ml
- 500ml
- 800ml
- 1l
- 8L
- 18L
- ManufacturerAlfa Aesar
- Product numberH52287
- Product description9-BBN monomer, 97%, 0.5M in THF
- Packaging100ml
- Price$47.6
- Updated2021-12-16
- Buy
- ManufacturerAlfa Aesar
- Product numberH52287
- Product description9-BBN monomer, 97%, 0.5M in THF
- Packaging500ml
- Price$180
- Updated2021-12-16
- Buy
- ManufacturerAlfa Aesar
- Product numberH52287
- Product description9-BBN monomer, 97% 0.5M in THF
- Packaging800ml
- Price$444
- Updated2021-12-16
- Buy
- ManufacturerAmerican Custom Chemicals Corporation
- Product numberBOR0011665
- Product description9-BORABICYCLO[3.3.1]NONANE SOLUTION (0.5M IN THF) 95.00%
- Packaging800ML
- Price$6549.43
- Updated2021-12-16
- Buy
- ManufacturerAmerican Custom Chemicals Corporation
- Product numberBOR0011665
- Product description9-BORABICYCLO[3.3.1]NONANE SOLUTION (0.5M IN THF) 95.00%
- Packaging8L
- Price$7249.94
- Updated2021-12-16
- Buy
- ManufacturerBiosynth Carbosynth
- Product numberFB11143
- Product description9-BBN monomer - 0.5M solution in THF
- Packaging100g
- Price$150
- Updated2021-12-16
- Buy
- ManufacturerSigma-Aldrich
- Product number151076
- Product description9-Borabicyclo[3.3.1]nonane solution 0.5 M in THF
- Packaging4x25ml
- Price$86.3
- Updated2024-03-01
- Buy
- ManufacturerSigma-Aldrich
- Product number151076
- Product description9-Borabicyclo[3.3.1]nonane solution 0.5 M in THF
- Packaging100ml
- Price$90.8
- Updated2024-03-01
- Buy
- ManufacturerSigma-Aldrich
- Product number459496
- Product description9-Borabicyclo[3.3.1]nonane solution 0.4 M in hexanes
- Packaging100ml
- Price$125
- Updated2024-03-01
- Buy
- ManufacturerSigma-Aldrich
- Product number151076
- Product description9-Borabicyclo[3.3.1]nonane solution 0.5 M in THF
- Packaging800ml
- Price$447
- Updated2024-03-01
- Buy
- ManufacturerSigma-Aldrich
- Product number459496
- Product description9-Borabicyclo[3.3.1]nonane solution 0.4 M in hexanes
- Packaging1l
- Price$1010
- Updated2023-06-20
- Buy
- ManufacturerSigma-Aldrich
- Product number151076
- Product description9-Borabicyclo[3.3.1]nonane solution 0.5?M in THF
- Packaging18L
- Price$2184
- Updated2024-03-01
- Buy
- ManufacturerSigma-Aldrich
- Product number151076
- Product description9-Borabicyclo[3.3.1]nonane solution 0.5 M in THF
- Packaging8l
- Price$2230
- Updated2024-03-01
- Buy
- ManufacturerTRC
- Product numberB675268
- Product description9-Borabicyclononane
- Packaging50ml
- Price$45
- Updated2021-12-16
- Buy
- ManufacturerTRC
- Product numberB675268
- Product description9-Borabicyclononane
- Packaging800ml
- Price$425
- Updated2021-12-16
- Buy
Manufacturer | Product number | Product description | Packaging | Price | Updated | Buy |
---|---|---|---|---|---|---|
Alfa Aesar | H52287 | 9-BBN monomer, 97%, 0.5M in THF | 100ml | $47.6 | 2021-12-16 | Buy |
Alfa Aesar | H52287 | 9-BBN monomer, 97%, 0.5M in THF | 500ml | $180 | 2021-12-16 | Buy |
Alfa Aesar | H52287 | 9-BBN monomer, 97% 0.5M in THF | 800ml | $444 | 2021-12-16 | Buy |
American Custom Chemicals Corporation | BOR0011665 | 9-BORABICYCLO[3.3.1]NONANE SOLUTION (0.5M IN THF) 95.00% | 800ML | $6549.43 | 2021-12-16 | Buy |
American Custom Chemicals Corporation | BOR0011665 | 9-BORABICYCLO[3.3.1]NONANE SOLUTION (0.5M IN THF) 95.00% | 8L | $7249.94 | 2021-12-16 | Buy |
Biosynth Carbosynth | FB11143 | 9-BBN monomer - 0.5M solution in THF | 100g | $150 | 2021-12-16 | Buy |
Sigma-Aldrich | 151076 | 9-Borabicyclo[3.3.1]nonane solution 0.5 M in THF | 4x25ml | $86.3 | 2024-03-01 | Buy |
Sigma-Aldrich | 151076 | 9-Borabicyclo[3.3.1]nonane solution 0.5 M in THF | 100ml | $90.8 | 2024-03-01 | Buy |
Sigma-Aldrich | 459496 | 9-Borabicyclo[3.3.1]nonane solution 0.4 M in hexanes | 100ml | $125 | 2024-03-01 | Buy |
Sigma-Aldrich | 151076 | 9-Borabicyclo[3.3.1]nonane solution 0.5 M in THF | 800ml | $447 | 2024-03-01 | Buy |
Sigma-Aldrich | 459496 | 9-Borabicyclo[3.3.1]nonane solution 0.4 M in hexanes | 1l | $1010 | 2023-06-20 | Buy |
Sigma-Aldrich | 151076 | 9-Borabicyclo[3.3.1]nonane solution 0.5?M in THF | 18L | $2184 | 2024-03-01 | Buy |
Sigma-Aldrich | 151076 | 9-Borabicyclo[3.3.1]nonane solution 0.5 M in THF | 8l | $2230 | 2024-03-01 | Buy |
TRC | B675268 | 9-Borabicyclononane | 50ml | $45 | 2021-12-16 | Buy |
TRC | B675268 | 9-Borabicyclononane | 800ml | $425 | 2021-12-16 | Buy |
Properties
Melting point :140-142 °C
Boiling point :68-70 °C
Density :0.894 g/mL at 25 °C
Flash point :1 °F
storage temp. :Flammables area
solubility :Miscible with ether, hexane, benzene, toluene, carbon tetrachloride, chloroform, dimethylsulfide and dichloromethane. Slightly miscible with cyclohexane, dimethoxyethane, diglyme and dioxane.
Water Solubility :reacts
Sensitive :Air & Moisture Sensitive
BRN :605509
Exposure limits :ACGIH: TWA 50 ppm; STEL 100 ppm (Skin)
OSHA: TWA 200 ppm(590 mg/m3)
NIOSH: IDLH 2000 ppm; TWA 200 ppm(590 mg/m3); STEL 250 ppm(735 mg/m3) InChIKey :FEJUGLKDZJDVFY-OCAPTIKFSA-N
EPA Substance Registry System :9-Borabicyclo[3.3.1]nonane (280-64-8)
Boiling point :68-70 °C
Density :0.894 g/mL at 25 °C
Flash point :1 °F
storage temp. :Flammables area
solubility :Miscible with ether, hexane, benzene, toluene, carbon tetrachloride, chloroform, dimethylsulfide and dichloromethane. Slightly miscible with cyclohexane, dimethoxyethane, diglyme and dioxane.
Water Solubility :reacts
Sensitive :Air & Moisture Sensitive
BRN :605509
Exposure limits :ACGIH: TWA 50 ppm; STEL 100 ppm (Skin)
OSHA: TWA 200 ppm(590 mg/m3)
NIOSH: IDLH 2000 ppm; TWA 200 ppm(590 mg/m3); STEL 250 ppm(735 mg/m3) InChIKey :FEJUGLKDZJDVFY-OCAPTIKFSA-N
EPA Substance Registry System :9-Borabicyclo[3.3.1]nonane (280-64-8)
Safety Information
Symbol(GHS): |
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Description
9-BBN monomer acts as a selective hydroboration reagent in synthetic organic chemistry. It is employed in Suzuki reactions as well as in the preparation of terminal alcohols by the region selective addition of alkenes followed by oxidative cleavage using hydrogen peroxide. It is also used in copper-catalyzed cross-coupling reactions of organoboron compounds with primary alkyl halides and pseudohalides. It acts as a protecting group for alkenes. Further, it is used as a reactant for Hetero-Diels-Alder reaction for the synthesis of spirocyclic alkaloids. In addition to this, it is used in intramolecular insertion of alkenes into palladium-nitrogen bonds.Related product price
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