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ChemicalBook >> CAS DataBase List >> (ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-2,2'-BIS[BIS(4-METHOXY-3,5-DIMETHYLPHENYL)PHOSPHINO]FERROCENE

(ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-2,2'-BIS[BIS(4-METHOXY-3,5-DIMETHYLPHENYL)PHOSPHINO]FERROCENE

(ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-2,2'-BIS[BIS(4-METHOXY-3,5-DIMETHYLPHENYL)PHOSPHINO]FERROCENE price.
  • $68 - $23440
  • Product name: (ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-2,2'-BIS[BIS(4-METHOXY-3,5-DIMETHYLPHENYL)PHOSPHINO]FERROCENE
  • CAS: 494227-37-1
  • MF: C64H74FeN2O4P210*
  • MW: 1053.08
  • EINECS:
  • MDL Number:MFCD04117704
  • Synonyms:MANDYPHOS SL-M004-1;(aR,aR)-1,1#-Bis[-(dimethylamino)benzyl]-(S,S)-2,2#-bis[bis(4-methoxy-3,5;(S,S)-(-)-2,2'-Bis((R)-(N,N-dimethylamino)-(phenyl)methyl)-1,1'-di(bis(3,5-dimethyl-4-methoxyphenyl)phosphino)ferrocene;(S,S)-(-)-2,2'-Bis[(R)-(N,N-dimethylamino)(phenyl)methyl]-1,1'-bis[di(3,5-dimethyl-4-methoxyphenyl)phosphino]ferrocene,min.97%;(r,r)-1,1'-bis[(r)-α-(dimethylamino)phenylmethyl]-2,2'-bis[bis(4-methoxy-3,5-dimethylphenyl)phosphino]ferrocene (acc to cas);(αr,αr)-1,1'-bis[α-(dimethylamino)benzyl]-(s,s)-2,2'-bis[bis(4-methoxy-3,5-dimethylphenyl)phosphino]ferrocene;(SP,SμP)-1,1μ-Bis[bis(4-methoxy-3,5-dimethylphenyl)phosphino]-2,2μ-bis[(R)-α-(dimethylamino)benzyl]ferrocene;Mandyphos SL-M004-1, (1R,1μR)- 1,1μ-Bis[bis(4-methoxy-3,5-dimethylphenyl)phosphino]-2,2μ-bis[(R)-(dimethylamino)phenylmethyl]ferrocene (acc to CAS)
20 prices
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Brand
  • AK Scientific
  • Ambeed
  • American Custom Chemicals Corporation
  • Crysdot
  • Sigma-Aldrich
  • Strem Chemicals
Package
  • 100mg
  • 250mg
  • 500mg
  • 1g
  • 2G
  • 5g
  • 10g
  • 50g
  • 100g
  • ManufacturerAK Scientific
  • Product number7540AJ
  • Product description(SP,S'P)-1,1'-Bis[bis(4-methoxy-3,5-dimethylphenyl)phosphino]-2,2'-bis[(R)-alpha-(dimethylamino)benzyl]ferrocene
  • Packaging500mg
  • Price$428
  • Updated2021-12-16
  • Buy
  • ManufacturerAmbeed
  • Product numberA606870
  • Product description(SP,S'P)-1,1'-Bis[bis(4-methoxy-3,5-dimethylphenyl)phosphino]-2,2'-bis[(R)-α-(dimethylamino)benzyl]ferrocene 98%
  • Packaging100mg
  • Price$68
  • Updated2021-12-16
  • Buy
  • ManufacturerAmbeed
  • Product numberA606870
  • Product description(SP,S'P)-1,1'-Bis[bis(4-methoxy-3,5-dimethylphenyl)phosphino]-2,2'-bis[(R)-α-(dimethylamino)benzyl]ferrocene 98%
  • Packaging250mg
  • Price$128
  • Updated2021-12-16
  • Buy
  • ManufacturerAmbeed
  • Product numberA606870
  • Product description(SP,S'P)-1,1'-Bis[bis(4-methoxy-3,5-dimethylphenyl)phosphino]-2,2'-bis[(R)-α-(dimethylamino)benzyl]ferrocene 98%
  • Packaging1g
  • Price$428
  • Updated2021-12-16
  • Buy
  • ManufacturerAmerican Custom Chemicals Corporation
  • Product numberING0001387
  • Product description(SP,S'P)-1,1'-BIS[BIS(4-METHOXY-3,5-DIMETHYLPHENYL)PHOSPHINO]-2,2'-BIS[(R)-ALPHA-(DIMETHYLAMINO)BENZYL]FERROCENE 95.00%
  • Packaging100MG
  • Price$646.88
  • Updated2021-12-16
  • Buy
  • ManufacturerAmerican Custom Chemicals Corporation
  • Product numberING0001387
  • Product description(SP,S'P)-1,1'-BIS[BIS(4-METHOXY-3,5-DIMETHYLPHENYL)PHOSPHINO]-2,2'-BIS[(R)-ALPHA-(DIMETHYLAMINO)BENZYL]FERROCENE 95.00%
  • Packaging500MG
  • Price$914.17
  • Updated2021-12-16
  • Buy
  • ManufacturerAmerican Custom Chemicals Corporation
  • Product numberING0001387
  • Product description(SP,S'P)-1,1'-BIS[BIS(4-METHOXY-3,5-DIMETHYLPHENYL)PHOSPHINO]-2,2'-BIS[(R)-ALPHA-(DIMETHYLAMINO)BENZYL]FERROCENE 95.00%
  • Packaging1G
  • Price$1269.75
  • Updated2021-12-16
  • Buy
  • ManufacturerAmerican Custom Chemicals Corporation
  • Product numberING0001387
  • Product description(SP,S'P)-1,1'-BIS[BIS(4-METHOXY-3,5-DIMETHYLPHENYL)PHOSPHINO]-2,2'-BIS[(R)-ALPHA-(DIMETHYLAMINO)BENZYL]FERROCENE 95.00%
  • Packaging2G
  • Price$1513
  • Updated2021-12-16
  • Buy
  • ManufacturerCrysdot
  • Product numberCD51000892
  • Product description(SP,S'P)-1,1'-Bis[bis(4-methoxy-3,5-dimethylphenyl)phosphino]-2,2'-bis[(R)-α-(dimethylamino)benzyl]ferrocene 97%
  • Packaging250mg
  • Price$195
  • Updated2021-12-16
  • Buy
  • ManufacturerCrysdot
  • Product numberCD51000892
  • Product description(SP,S'P)-1,1'-Bis[bis(4-methoxy-3,5-dimethylphenyl)phosphino]-2,2'-bis[(R)-α-(dimethylamino)benzyl]ferrocene 97%
  • Packaging1g
  • Price$490
  • Updated2021-12-16
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number73469
  • Product description(SP,S′P)-1,1′-Bis[bis(4-methoxy-3,5-dimethylphenyl)phosphino]-2,2′-bis[(R)-α-(dimethylamino)benzyl]ferrocene ≥97%
  • Packaging100mg
  • Price$96.8
  • Updated2024-03-01
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number73469
  • Product description(SP,S′P)-1,1′-Bis[bis(4-methoxy-3,5-dimethylphenyl)phosphino]-2,2′-bis[(R)-α-(dimethylamino)benzyl]ferrocene ≥97%
  • Packaging500mg
  • Price$363
  • Updated2023-06-20
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number73469
  • Product description(SP,S′P)-1,1′-Bis[bis(4-methoxy-3,5-dimethylphenyl)phosphino]-2,2′-bis[(R)-α-(dimethylamino)benzyl]ferrocene ≥97%
  • Packaging1g
  • Price$718
  • Updated2024-03-01
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number73469
  • Product description(SP,S′P)-1,1′-Bis[bis(4-methoxy-3,5-dimethylphenyl)phosphino]-2,2′-bis[(R)-α-(dimethylamino)benzyl]ferrocene ≥97%
  • Packaging5g
  • Price$2370
  • Updated2023-01-07
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number73469
  • Product description(SP,S′P)-1,1′-Bis[bis(4-methoxy-3,5-dimethylphenyl)phosphino]-2,2′-bis[(R)-α-(dimethylamino)benzyl]ferrocene ≥97%
  • Packaging50g
  • Price$21310
  • Updated2024-03-01
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number73469
  • Product description(SP,S′P)-1,1′-Bis[bis(4-methoxy-3,5-dimethylphenyl)phosphino]-2,2′-bis[(R)-α-(dimethylamino)benzyl]ferrocene ≥97%
  • Packaging100g
  • Price$23440
  • Updated2024-03-01
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
AK Scientific 7540AJ (SP,S'P)-1,1'-Bis[bis(4-methoxy-3,5-dimethylphenyl)phosphino]-2,2'-bis[(R)-alpha-(dimethylamino)benzyl]ferrocene 500mg $428 2021-12-16 Buy
Ambeed A606870 (SP,S'P)-1,1'-Bis[bis(4-methoxy-3,5-dimethylphenyl)phosphino]-2,2'-bis[(R)-α-(dimethylamino)benzyl]ferrocene 98% 100mg $68 2021-12-16 Buy
Ambeed A606870 (SP,S'P)-1,1'-Bis[bis(4-methoxy-3,5-dimethylphenyl)phosphino]-2,2'-bis[(R)-α-(dimethylamino)benzyl]ferrocene 98% 250mg $128 2021-12-16 Buy
Ambeed A606870 (SP,S'P)-1,1'-Bis[bis(4-methoxy-3,5-dimethylphenyl)phosphino]-2,2'-bis[(R)-α-(dimethylamino)benzyl]ferrocene 98% 1g $428 2021-12-16 Buy
American Custom Chemicals Corporation ING0001387 (SP,S'P)-1,1'-BIS[BIS(4-METHOXY-3,5-DIMETHYLPHENYL)PHOSPHINO]-2,2'-BIS[(R)-ALPHA-(DIMETHYLAMINO)BENZYL]FERROCENE 95.00% 100MG $646.88 2021-12-16 Buy
American Custom Chemicals Corporation ING0001387 (SP,S'P)-1,1'-BIS[BIS(4-METHOXY-3,5-DIMETHYLPHENYL)PHOSPHINO]-2,2'-BIS[(R)-ALPHA-(DIMETHYLAMINO)BENZYL]FERROCENE 95.00% 500MG $914.17 2021-12-16 Buy
American Custom Chemicals Corporation ING0001387 (SP,S'P)-1,1'-BIS[BIS(4-METHOXY-3,5-DIMETHYLPHENYL)PHOSPHINO]-2,2'-BIS[(R)-ALPHA-(DIMETHYLAMINO)BENZYL]FERROCENE 95.00% 1G $1269.75 2021-12-16 Buy
American Custom Chemicals Corporation ING0001387 (SP,S'P)-1,1'-BIS[BIS(4-METHOXY-3,5-DIMETHYLPHENYL)PHOSPHINO]-2,2'-BIS[(R)-ALPHA-(DIMETHYLAMINO)BENZYL]FERROCENE 95.00% 2G $1513 2021-12-16 Buy
Crysdot CD51000892 (SP,S'P)-1,1'-Bis[bis(4-methoxy-3,5-dimethylphenyl)phosphino]-2,2'-bis[(R)-α-(dimethylamino)benzyl]ferrocene 97% 250mg $195 2021-12-16 Buy
Crysdot CD51000892 (SP,S'P)-1,1'-Bis[bis(4-methoxy-3,5-dimethylphenyl)phosphino]-2,2'-bis[(R)-α-(dimethylamino)benzyl]ferrocene 97% 1g $490 2021-12-16 Buy
Sigma-Aldrich 73469 (SP,S′P)-1,1′-Bis[bis(4-methoxy-3,5-dimethylphenyl)phosphino]-2,2′-bis[(R)-α-(dimethylamino)benzyl]ferrocene ≥97% 100mg $96.8 2024-03-01 Buy
Sigma-Aldrich 73469 (SP,S′P)-1,1′-Bis[bis(4-methoxy-3,5-dimethylphenyl)phosphino]-2,2′-bis[(R)-α-(dimethylamino)benzyl]ferrocene ≥97% 500mg $363 2023-06-20 Buy
Sigma-Aldrich 73469 (SP,S′P)-1,1′-Bis[bis(4-methoxy-3,5-dimethylphenyl)phosphino]-2,2′-bis[(R)-α-(dimethylamino)benzyl]ferrocene ≥97% 1g $718 2024-03-01 Buy
Sigma-Aldrich 73469 (SP,S′P)-1,1′-Bis[bis(4-methoxy-3,5-dimethylphenyl)phosphino]-2,2′-bis[(R)-α-(dimethylamino)benzyl]ferrocene ≥97% 5g $2370 2023-01-07 Buy
Sigma-Aldrich 73469 (SP,S′P)-1,1′-Bis[bis(4-methoxy-3,5-dimethylphenyl)phosphino]-2,2′-bis[(R)-α-(dimethylamino)benzyl]ferrocene ≥97% 50g $21310 2024-03-01 Buy
Sigma-Aldrich 73469 (SP,S′P)-1,1′-Bis[bis(4-methoxy-3,5-dimethylphenyl)phosphino]-2,2′-bis[(R)-α-(dimethylamino)benzyl]ferrocene ≥97% 100g $23440 2024-03-01 Buy

Properties

alpha :-61.5° (c 1.0, CHCl3)
form :solid
color :yellow to orange-red
Stability :store cold

Safety Information

Symbol(GHS): GHS hazard pictograms
Signal word: Warning
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H302 Harmful if swallowed Acute toxicity,oral Category 4 Warning GHS hazard pictograms P264, P270, P301+P312, P330, P501
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning GHS hazard pictograms
Precautionary statements:
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Description

It may be used as a chiral ligand in the rhodium complex-catalyzed hydrogenation reaction, a key step during the synthesis of argatroban.

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