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ChemicalBook >> CAS DataBase List >> (S)-TRIP, (11bS)-4-Hydroxy-2,6-bis[2,4,6-tris(1-methylethyl)phenyl]dinaphtho[2,1-d:1μ,2μ-f]-1,3,2-dioxaphosphepin 4-oxide, (S)-3,3μ-Bis(2,4,6-triisopropylphenyl)-1,1μ-bi-2-naphthol cyclic monophosphate

(S)-TRIP, (11bS)-4-Hydroxy-2,6-bis[2,4,6-tris(1-methylethyl)phenyl]dinaphtho[2,1-d:1μ,2μ-f]-1,3,2-dioxaphosphepin 4-oxide, (S)-3,3μ-Bis(2,4,6-triisopropylphenyl)-1,1μ-bi-2-naphthol cyclic monophosphate

(S)-TRIP,  (11bS)-4-Hydroxy-2,6-bis[2,4,6-tris(1-methylethyl)phenyl]dinaphtho[2,1-d:1μ,2μ-f]-1,3,2-dioxaphosphepin  4-oxide,  (S)-3,3μ-Bis(2,4,6-triisopropylphenyl)-1,1μ-bi-2-naphthol  cyclic  monophosphate price.
  • $68 - $2599.8
  • Product name: (S)-TRIP, (11bS)-4-Hydroxy-2,6-bis[2,4,6-tris(1-methylethyl)phenyl]dinaphtho[2,1-d:1μ,2μ-f]-1,3,2-dioxaphosphepin 4-oxide, (S)-3,3μ-Bis(2,4,6-triisopropylphenyl)-1,1μ-bi-2-naphthol cyclic monophosphate
  • CAS: 874948-63-7
  • MF: C50H57O4P
  • MW: 752.96
  • EINECS:
  • MDL Number:MFCD10567009
  • Synonyms:(S)-TRIP, (11bS)-4-Hydroxy-2,6-bis[2,4,6-tris(1-methylethyl)phenyl]dinaphtho[2,1-d:1μ,2μ-f]-1,3,2-dioxaphosphepin 4-oxide, (S)-3,3μ-Bis(2,4,6-triisopropylphenyl)-1,1μ-bi-2-naphthol cyclic monophosphate;(S)-TRIP;(S)-3,3'-Bis(2,4,6-triisopropylphenyl)-1,1'-binaphthyl-2,2'-diyl hydrogenphosphate >=97.5% (HPLC);(S)-3,3'-Bis(2,4,6-trisopropylphenyl)-1,1'-binapthyl-2,2'-diyl hydrogenphosphate;(S)-3,3'-Bis(2,4,6-triIsopropylphenyl)-1,1'-binapthyl-2,2'-diylhydrogenphosphate;(11bS)-4-Hydroxy-2,6-bis[2,4,6-tris(1-methylethyl)phenyl]-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin 4-oxide;(11bS)-4-Hydroxy-2,6-bis(2,4,6-triisopropylphenyl)dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine 4-oxide;(S)-3,3'-Bis(2,4,6-triisopropylphenyl)-1,1'-binaphthyl-2,2'- diyl Hydrogen Phosphate,99%e.e.
23 prices
Selected condition:
Brand
  • AK Scientific
  • Alichem
  • Ambeed
  • ChemScene
  • Crysdot
  • Matrix Scientific
  • Sigma-Aldrich
  • Strem Chemicals
  • SynQuest Laboratories
Package
  • 25mg
  • 100mg
  • 250mg
  • 500mg
  • 1g
  • 5g
  • 10g
  • ManufacturerAK Scientific
  • Product number2222AQ
  • Product description(S)-TRIP
  • Packaging100mg
  • Price$484.4
  • Updated2021-12-16
  • Buy
  • ManufacturerAlichem
  • Product number874948637
  • Product description(11bS)-4-Hydroxy-2,6-bis(2,4,6-triisopropylphenyl)dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine4-oxide
  • Packaging100mg
  • Price$631.38
  • Updated2021-12-16
  • Buy
  • ManufacturerAlichem
  • Product number874948637
  • Product description(11bS)-4-Hydroxy-2,6-bis(2,4,6-triisopropylphenyl)dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine4-oxide
  • Packaging250mg
  • Price$960.3
  • Updated2021-12-16
  • Buy
  • ManufacturerAlichem
  • Product number874948637
  • Product description(11bS)-4-Hydroxy-2,6-bis(2,4,6-triisopropylphenyl)dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine4-oxide
  • Packaging1g
  • Price$2599.8
  • Updated2021-12-16
  • Buy
  • ManufacturerAmbeed
  • Product numberA1324845
  • Product description(11bS)-4-Hydroxy-2,6-bis(2,4,6-triisopropylphenyl)dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine4-oxide 98%+99%ee
  • Packaging100mg
  • Price$68
  • Updated2021-12-16
  • Buy
  • ManufacturerAmbeed
  • Product numberA1324845
  • Product description(11bS)-4-Hydroxy-2,6-bis(2,4,6-triisopropylphenyl)dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine4-oxide 98%+99%ee
  • Packaging250mg
  • Price$128
  • Updated2021-12-16
  • Buy
  • ManufacturerAmbeed
  • Product numberA1324845
  • Product description(11bS)-4-Hydroxy-2,6-bis(2,4,6-triisopropylphenyl)dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine4-oxide 98%+99%ee
  • Packaging1g
  • Price$428
  • Updated2021-12-16
  • Buy
  • ManufacturerAmbeed
  • Product numberA1324845
  • Product description(11bS)-4-Hydroxy-2,6-bis(2,4,6-triisopropylphenyl)dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine4-oxide 98%+99%ee
  • Packaging5g
  • Price$1280
  • Updated2021-12-16
  • Buy
  • ManufacturerAmbeed
  • Product numberA1324845
  • Product description(11bS)-4-Hydroxy-2,6-bis(2,4,6-triisopropylphenyl)dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine4-oxide 98%+99%ee
  • Packaging10g
  • Price$1964
  • Updated2021-12-16
  • Buy
  • ManufacturerChemScene
  • Product numberCS-W020708
  • Product description(S)-TRIP ≥98.0%
  • Packaging250mg
  • Price$128
  • Updated2021-12-16
  • Buy
  • ManufacturerChemScene
  • Product numberCS-W020708
  • Product description(S)-TRIP ≥98.0%
  • Packaging1g
  • Price$428
  • Updated2021-12-16
  • Buy
  • ManufacturerChemScene
  • Product numberCS-W020708
  • Product description(S)-TRIP ≥98.0%
  • Packaging5g
  • Price$1280
  • Updated2021-12-16
  • Buy
  • ManufacturerCrysdot
  • Product numberCD51000219
  • Product description(11bS)-4-Hydroxy-2,6-bis(2,4,6-triisopropylphenyl)dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine4-oxide 95+%
  • Packaging25mg
  • Price$307
  • Updated2021-12-16
  • Buy
  • ManufacturerCrysdot
  • Product numberCD51000219
  • Product description(11bS)-4-Hydroxy-2,6-bis(2,4,6-triisopropylphenyl)dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine4-oxide 95+%
  • Packaging100mg
  • Price$613
  • Updated2021-12-16
  • Buy
  • ManufacturerCrysdot
  • Product numberCD51000219
  • Product description(11bS)-4-Hydroxy-2,6-bis(2,4,6-triisopropylphenyl)dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine4-oxide 95+%
  • Packaging250mg
  • Price$980
  • Updated2021-12-16
  • Buy
  • ManufacturerCrysdot
  • Product numberCD51000219
  • Product description(11bS)-4-Hydroxy-2,6-bis(2,4,6-triisopropylphenyl)dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine4-oxide 95+%
  • Packaging1g
  • Price$2452
  • Updated2021-12-16
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
AK Scientific 2222AQ (S)-TRIP 100mg $484.4 2021-12-16 Buy
Alichem 874948637 (11bS)-4-Hydroxy-2,6-bis(2,4,6-triisopropylphenyl)dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine4-oxide 100mg $631.38 2021-12-16 Buy
Alichem 874948637 (11bS)-4-Hydroxy-2,6-bis(2,4,6-triisopropylphenyl)dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine4-oxide 250mg $960.3 2021-12-16 Buy
Alichem 874948637 (11bS)-4-Hydroxy-2,6-bis(2,4,6-triisopropylphenyl)dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine4-oxide 1g $2599.8 2021-12-16 Buy
Ambeed A1324845 (11bS)-4-Hydroxy-2,6-bis(2,4,6-triisopropylphenyl)dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine4-oxide 98%+99%ee 100mg $68 2021-12-16 Buy
Ambeed A1324845 (11bS)-4-Hydroxy-2,6-bis(2,4,6-triisopropylphenyl)dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine4-oxide 98%+99%ee 250mg $128 2021-12-16 Buy
Ambeed A1324845 (11bS)-4-Hydroxy-2,6-bis(2,4,6-triisopropylphenyl)dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine4-oxide 98%+99%ee 1g $428 2021-12-16 Buy
Ambeed A1324845 (11bS)-4-Hydroxy-2,6-bis(2,4,6-triisopropylphenyl)dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine4-oxide 98%+99%ee 5g $1280 2021-12-16 Buy
Ambeed A1324845 (11bS)-4-Hydroxy-2,6-bis(2,4,6-triisopropylphenyl)dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine4-oxide 98%+99%ee 10g $1964 2021-12-16 Buy
ChemScene CS-W020708 (S)-TRIP ≥98.0% 250mg $128 2021-12-16 Buy
ChemScene CS-W020708 (S)-TRIP ≥98.0% 1g $428 2021-12-16 Buy
ChemScene CS-W020708 (S)-TRIP ≥98.0% 5g $1280 2021-12-16 Buy
Crysdot CD51000219 (11bS)-4-Hydroxy-2,6-bis(2,4,6-triisopropylphenyl)dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine4-oxide 95+% 25mg $307 2021-12-16 Buy
Crysdot CD51000219 (11bS)-4-Hydroxy-2,6-bis(2,4,6-triisopropylphenyl)dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine4-oxide 95+% 100mg $613 2021-12-16 Buy
Crysdot CD51000219 (11bS)-4-Hydroxy-2,6-bis(2,4,6-triisopropylphenyl)dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine4-oxide 95+% 250mg $980 2021-12-16 Buy
Crysdot CD51000219 (11bS)-4-Hydroxy-2,6-bis(2,4,6-triisopropylphenyl)dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine4-oxide 95+% 1g $2452 2021-12-16 Buy

Properties

Boiling point :814.2±75.0 °C(Predicted)
Density :1.17±0.1 g/cm3(Predicted)
storage temp. :Inert atmosphere,Room Temperature
pka :1.12±0.20(Predicted)
form :Powder
color :white to light-yellow

Safety Information

Symbol(GHS): GHS hazard pictograms
Signal word: Warning
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
Precautionary statements:
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P271 Use only outdoors or in a well-ventilated area.

Description

Versatile organocatalyst. Uses include asymmetric reductive amination, enantioselective Diels-Alder reactions and asymmetric counteranion-directed catalysis (ACDC). Can be used in cooperation with chiral iridium complexes to catalyze greener asymmetric reductive amination using hydrogen gas.

Metal-Br?nsted Acid Cooperative Catalysis for Asymmetric Reductive Amination