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ChemicalBook >> CAS DataBase List >> Dimethylammonium dichlorotri(chloro)bis{(R)-(+)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}diruthenate(II) [NH2Me2][{RuCl((R)-dm-segphos)}2(Cl)3]

Dimethylammonium dichlorotri(chloro)bis{(R)-(+)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}diruthenate(II) [NH2Me2][{RuCl((R)-dm-segphos)}2(Cl)3]

Dimethylammonium dichlorotri(chloro)bis{(R)-(+)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}diruthenate(II) [NH2Me2][{RuCl((R)-dm-segphos)}2(Cl)3] price.
  • $25.2 - $498.34
  • Product name: Dimethylammonium dichlorotri(chloro)bis{(R)-(+)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}diruthenate(II) [NH2Me2][{RuCl((R)-dm-segphos)}2(Cl)3]
  • CAS: 935449-46-0
  • MF: C94H100Cl5NO8P4Ru2
  • MW: 1875.12
  • EINECS:
  • MDL Number:MFCD09753038
  • Synonyms:Dimethylammonium dichlorotri(chloro)bis{(R)-(+)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}diruthenate(II) [NH2Me2][{RuCl((R)-dm-segphos)}2(Cl)3];DiMethylaMMoniuM dichlorotri(Mu-chloro)bis{(R)-(+)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}diruthenate(II) [NH2Me2][{RuCl((R)-dM-segphos)}2(μ-Cl)3];(R)[(RuCl(DMSEGPHOS)2(μCl)3][NH2Me2];(R)-[(RUCL(DM-SEGPHOS)2(Μ-CL)3][NH2ME2];[NH2Me2][(RuCl((R)-dm-segphos(regR)))2(mu-Cl)3];[NH2ME2][(RUCL((R)-DM-SEGPHOS))2(Μ-CL)3];Dimethylammonium dichlorotri(μ-chloro)bis{(R)-(+)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}diruthenate(II) [NH2Me2][{RuCl((R)-dm-segphos(R))}2(μ-Cl)3];[NH2Me2][(RuCl((R)-dm-segphos[R]))2(μ-Cl)3]
Price9 Properties Safety Information Description
9 prices
Selected condition：
Brand
  • American Custom Chemicals Corporation
  • Chem-Impex
  • Sigma-Aldrich
  • Strem Chemicals
  • TCI Chemical
Package
  • 5MG
  • 50mg
  • 100mg
  • 200MG
  • 250mg
  • 1g
  • 5g
  • ManufacturerAmerican Custom Chemicals Corporation
  • Product numberING0013155
  • Product descriptionDIMETHYLAMMONIUM DICHLORO-TRI-(MU-CHLORO)-BIS-[(R)-(+)-5,5'-BIS[DI-(3,5-XYLYL)PHOSPHINO]-4,4'-BI-1,3-BENZODIOXOLE]DI-RUTHENATE-(II) 95.00%
  • Packaging5MG
  • Price$498.34
  • Updated2021-12-16
  • Buy
  • ManufacturerChem-Impex
  • Product number40785
  • Product description[NH2Me2][(RuCl((R)-dm-segphos))2(m-Cl)3]
  • Packaging200MG
  • Price$67.56
  • Updated2021-12-16
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number692212
  • Product description(R)?[(RuCl(DM?SEGPHOS?)2(μ?Cl)3][NH2Me2]
  • Packaging50mg
  • Price$25.2
  • Updated2023-06-20
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number692212
  • Product description(R)?[(RuCl(DM?SEGPHOS?)2(μ?Cl)3][NH2Me2]
  • Packaging100mg
  • Price$45
  • Updated2023-01-07
  • Buy
  • ManufacturerStrem Chemicals
  • Product number44-0520
  • Product descriptionDimethylammonium dichlorotri(μ-chloro)bis{(R)-(+)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}diruthenate(II) [NH2Me2][{RuCl((R)-dm-segphos(R))}2(μ-Cl)3]
  • Packaging250mg
  • Price$64
  • Updated2024-03-01
  • Buy
  • ManufacturerStrem Chemicals
  • Product number44-0520
  • Product descriptionDimethylammonium dichlorotri(μ-chloro)bis{(R)-(+)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}diruthenate(II) [NH2Me2][{RuCl((R)-dm-segphos(R))}2(μ-Cl)3]
  • Packaging1g
  • Price$190
  • Updated2024-03-01
  • Buy
  • ManufacturerStrem Chemicals
  • Product number44-0520
  • Product descriptionDimethylammonium dichlorotri(μ-chloro)bis{(R)-(+)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}diruthenate(II) [NH2Me2][{RuCl((R)-dm-segphos(R))}2(μ-Cl)3]
  • Packaging5g
  • Price$474
  • Updated2024-03-01
  • Buy
  • ManufacturerTCI Chemical
  • Product numberN1023
  • Product description[NH2Me2][(RuCl((R)-dm-segphos(regR)))2(mu-Cl)3]
  • Packaging200mg
  • Price$59
  • Updated2024-03-01
  • Buy
  • ManufacturerTCI Chemical
  • Product numberN1023
  • Product description[NH2Me2][(RuCl((R)-dm-segphos(regR)))2(mu-Cl)3]
  • Packaging1g
  • Price$203
  • Updated2024-03-01
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
American Custom Chemicals Corporation ING0013155 DIMETHYLAMMONIUM DICHLORO-TRI-(MU-CHLORO)-BIS-[(R)-(+)-5,5'-BIS[DI-(3,5-XYLYL)PHOSPHINO]-4,4'-BI-1,3-BENZODIOXOLE]DI-RUTHENATE-(II) 95.00% 5MG $498.34 2021-12-16 Buy
Chem-Impex 40785 [NH2Me2][(RuCl((R)-dm-segphos))2(m-Cl)3] 200MG $67.56 2021-12-16 Buy
Sigma-Aldrich 692212 (R)?[(RuCl(DM?SEGPHOS?)2(μ?Cl)3][NH2Me2] 50mg $25.2 2023-06-20 Buy
Sigma-Aldrich 692212 (R)?[(RuCl(DM?SEGPHOS?)2(μ?Cl)3][NH2Me2] 100mg $45 2023-01-07 Buy
Strem Chemicals 44-0520 Dimethylammonium dichlorotri(μ-chloro)bis{(R)-(+)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}diruthenate(II) [NH2Me2][{RuCl((R)-dm-segphos(R))}2(μ-Cl)3] 250mg $64 2024-03-01 Buy
Strem Chemicals 44-0520 Dimethylammonium dichlorotri(μ-chloro)bis{(R)-(+)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}diruthenate(II) [NH2Me2][{RuCl((R)-dm-segphos(R))}2(μ-Cl)3] 1g $190 2024-03-01 Buy
Strem Chemicals 44-0520 Dimethylammonium dichlorotri(μ-chloro)bis{(R)-(+)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}diruthenate(II) [NH2Me2][{RuCl((R)-dm-segphos(R))}2(μ-Cl)3] 5g $474 2024-03-01 Buy
TCI Chemical N1023 [NH2Me2][(RuCl((R)-dm-segphos(regR)))2(mu-Cl)3] 200mg $59 2024-03-01 Buy
TCI Chemical N1023 [NH2Me2][(RuCl((R)-dm-segphos(regR)))2(mu-Cl)3] 1g $203 2024-03-01 Buy

Properties

Melting point :>100°C
storage temp. :2-8°C
Water Solubility :Insoluble in water
form :Powder
color :light brown
Sensitive :air sensitive

Safety Information

Symbol(GHS): GHS hazard pictograms
Signal word: Warning
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning GHS hazard pictograms
Precautionary statements:
P264 Wash hands thoroughly after handling.
P264 Wash skin thouroughly after handling.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352 IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P321 Specific treatment (see … on this label).
P332+P313 IF SKIN irritation occurs: Get medical advice/attention.
P362 Take off contaminated clothing and wash before reuse.

Description

(R)-[(RuCl(DM-SEGPHOS?)2(μ-Cl)3][NH2Me2] can be used as a catalyst for the asymmetric hydrogenation of ketones to chiral alcohols. It can also be utilized to prepare (R)-methyl-3-hydroxybutanoate from methyl acetoacetate via stereoselective hydrogenation reaction.

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Suppliers and manufacturers

Aladdin Scientific
Amadis Chemical Company Limited J & K SCIENTIFIC LTD. TCI (Shanghai) Development Co., Ltd. Energy Chemical TOKYO CHEMICAL INDUSTRY CO., LTD. TCI Europe TCI AMERICA Shanghai Aladdin Bio-Chem Technology Co.,LTD Sigma-Aldrich