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ChemicalBook >> CAS DataBase List >> 4-(METHOXYCARBONYL)PHENYLBORONIC ACID

4-(METHOXYCARBONYL)PHENYLBORONIC ACID

4-(METHOXYCARBONYL)PHENYLBORONIC ACID price.
  • $10 - $1685
  • Product name: 4-(METHOXYCARBONYL)PHENYLBORONIC ACID
  • CAS: 99768-12-4
  • MF: C8H9BO4
  • MW: 179.97
  • EINECS:619-459-9
  • MDL Number:MFCD01632203
  • Synonyms:RARECHEM AH PB 0115;P-(METHOXYCARBONYL)PHENYLBORONIC ACID;AKOS BRN-0122;4-METHOXYCARBONYLBENZENEBORONIC ACID;4-CARBOMETHOXYPHENYLBORONIC ACID;Methyl 4-boronobenzoate 4-(Methoxycarbonyl)phenylboronic acid;4-METHOXYCATBONYLPHENYLBORONICACID;4-(Methoxycabonyl)phenylboronic acid
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  • Acrotein
  • AHH
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  • ManufacturerAcrotein
  • Product numberPB-0082
  • Product description4-Methoxycarbonylphenylboronic acid 97%
  • Packaging25g
  • Price$66.73
  • Updated2021-12-16
  • Buy
  • ManufacturerAHH
  • Product numberMT-16793
  • Product description4-Methoxycarbonylphenylboronic acid 97%
  • Packaging100g
  • Price$538
  • Updated2021-12-16
  • Buy
  • ManufacturerAK Scientific
  • Product numberJ90625
  • Product description4-Methoxycarbonylphenylboronic acid
  • Packaging5g
  • Price$15
  • Updated2021-12-16
  • Buy
  • ManufacturerAK Scientific
  • Product numberC196
  • Product description4-Methoxycarbonylphenylboronic acid
  • Packaging25g
  • Price$54
  • Updated2021-12-16
  • Buy
  • ManufacturerAlfa Aesar
  • Product numberH27627
  • Product description4-(Methoxycarbonyl)benzeneboronic acid, 97%
  • Packaging1g
  • Price$61.65
  • Updated2024-03-01
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  • ManufacturerAlfa Aesar
  • Product numberH27627
  • Product description4-(Methoxycarbonyl)benzeneboronic acid, 97%
  • Packaging5g
  • Price$210
  • Updated2024-03-01
  • Buy
  • ManufacturerAlichem
  • Product number99768124
  • Product description4-Methoxycarbonylphenylboronic acid
  • Packaging250mg
  • Price$680
  • Updated2021-12-16
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  • ManufacturerAlichem
  • Product number99768124
  • Product description4-Methoxycarbonylphenylboronic acid
  • Packaging500mg
  • Price$980
  • Updated2021-12-16
  • Buy
  • ManufacturerAlichem
  • Product number99768124
  • Product description4-Methoxycarbonylphenylboronic acid
  • Packaging1g
  • Price$1685
  • Updated2021-12-16
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  • ManufacturerAmerican Custom Chemicals Corporation
  • Product numberBOR0001366
  • Product description4-(METHOXYCARBONYL)PHENYL BORONIC ACID 95.00%
  • Packaging0.5G
  • Price$605
  • Updated2021-12-16
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  • ManufacturerAOBChem
  • Product number10265
  • Product description4-Methoxycarbonylphenylboronic acid 97%
  • Packaging50g
  • Price$81
  • Updated2021-12-16
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  • ManufacturerAOBChem
  • Product number10265
  • Product description4-Methoxycarbonylphenylboronic acid 97%
  • Packaging100g
  • Price$130
  • Updated2021-12-16
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  • ManufacturerApolloscientific
  • Product numberOR5354
  • Product description4-(Methoxycarbonyl)benzeneboronicacid 98%
  • Packaging5g
  • Price$18
  • Updated2021-12-16
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  • ManufacturerApolloscientific
  • Product numberOR5354
  • Product description4-(Methoxycarbonyl)benzeneboronicacid 98%
  • Packaging25g
  • Price$51
  • Updated2021-12-16
  • Buy
  • ManufacturerApolloscientific
  • Product numberOR5354
  • Product description4-(Methoxycarbonyl)benzeneboronicacid 98%
  • Packaging100g
  • Price$138
  • Updated2021-12-16
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  • ManufacturerChem-Impex
  • Product number31434
  • Product description4-Methoxycarbonylphenylboronicacid,98-100%(HPLC) 98-100%(HPLC)
  • Packaging5G
  • Price$16.8
  • Updated2021-12-16
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
Acrotein PB-0082 4-Methoxycarbonylphenylboronic acid 97% 25g $66.73 2021-12-16 Buy
AHH MT-16793 4-Methoxycarbonylphenylboronic acid 97% 100g $538 2021-12-16 Buy
AK Scientific J90625 4-Methoxycarbonylphenylboronic acid 5g $15 2021-12-16 Buy
AK Scientific C196 4-Methoxycarbonylphenylboronic acid 25g $54 2021-12-16 Buy
Alfa Aesar H27627 4-(Methoxycarbonyl)benzeneboronic acid, 97% 1g $61.65 2024-03-01 Buy
Alfa Aesar H27627 4-(Methoxycarbonyl)benzeneboronic acid, 97% 5g $210 2024-03-01 Buy
Alichem 99768124 4-Methoxycarbonylphenylboronic acid 250mg $680 2021-12-16 Buy
Alichem 99768124 4-Methoxycarbonylphenylboronic acid 500mg $980 2021-12-16 Buy
Alichem 99768124 4-Methoxycarbonylphenylboronic acid 1g $1685 2021-12-16 Buy
American Custom Chemicals Corporation BOR0001366 4-(METHOXYCARBONYL)PHENYL BORONIC ACID 95.00% 0.5G $605 2021-12-16 Buy
AOBChem 10265 4-Methoxycarbonylphenylboronic acid 97% 50g $81 2021-12-16 Buy
AOBChem 10265 4-Methoxycarbonylphenylboronic acid 97% 100g $130 2021-12-16 Buy
Apolloscientific OR5354 4-(Methoxycarbonyl)benzeneboronicacid 98% 5g $18 2021-12-16 Buy
Apolloscientific OR5354 4-(Methoxycarbonyl)benzeneboronicacid 98% 25g $51 2021-12-16 Buy
Apolloscientific OR5354 4-(Methoxycarbonyl)benzeneboronicacid 98% 100g $138 2021-12-16 Buy
Chem-Impex 31434 4-Methoxycarbonylphenylboronicacid,98-100%(HPLC) 98-100%(HPLC) 5G $16.8 2021-12-16 Buy

Properties

Melting point :197-200 °C (lit.)
Boiling point :345.8±44.0 °C(Predicted)
Density :1.25±0.1 g/cm3(Predicted)
storage temp. :Inert atmosphere,Room Temperature
solubility :Soluble in methanol.
form :powder
pka :7.69±0.10(Predicted)
color :white to off-white
InChI :InChI=1S/C8H9BO4/c1-13-8(10)6-2-4-7(5-3-6)9(11)12/h2-5,11-12H,1H3
InChIKey :PQCXFUXRTRESBD-UHFFFAOYSA-N
SMILES :C1=CC(C(OC)=O)=CC=C1B(O)O
CAS DataBase Reference :99768-12-4(CAS DataBase Reference)

Safety Information

Symbol(GHS): GHS hazard pictograms
Signal word: Warning
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning GHS hazard pictograms
Precautionary statements:
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P304+P340 IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P405 Store locked up.

Description

It is a reagent used for tandem-type Pd(II)-catalyzed oxidative Heck reaction and intramolecular C-H amidation sequence, copper-mediated ligandless aerobic fluoroalkylation of arylboronic acids with fluoroalkyl iodides, one-pot ipso-nitration of arylboronic acids, copper-catalyzed nitration and cyclocondensation followed by palladium-phosphine-catalyzed Suzuki-Miyaura coupling. It is employed as reagent in Reagent used in preparation of biaryls via nickel-catalyzed Suzuki-Miyaura cross-coupling reaction of aryl halides with arylboronic acid, chromenones and their bradykinin B1 antagonistic activity, Pt nanoparticles on Photoactive metal-organic frameworks resulting in efficient hydrogen evolution via synergistic photoexcitation and electron injection and salicylate-based thienylbenzoic acids as E. coli methionine aminopeptidase inhibitor.

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