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ChemicalBook >> CAS DataBase List >> BrettPhos Pd G3

BrettPhos Pd G3

BrettPhos Pd G3 price.
  • $13 - $1945
  • Product name: BrettPhos Pd G3
  • CAS: 1470372-59-8
  • MF: C48H66NO5PPdS
  • MW: 906.51
  • EINECS:
  • MDL Number:MFCD22572666
  • Synonyms:Methanesulfonato2-Dicyclohexylphosphino-3,6-dimethoxy-2'-4' -6'-tri-i-propyl-1,1'-bipheny)(2'-amino-1,1'-biphenyl-2-yl)palladium(II);BrettPhos Pd G3 95%;[2'-(Amino)[1,1'-biphenyl]-2-yl][dicyclohexyl[3,6-dimethoxy-2',4',6'-tris(1-methylethyl)[1,1'-biphenyl]-2-yl]phosphine](methanesulfonato)palladium;Methanesulfonato(2-dicyclohexylphosphino-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladiu;[2'-(Amino-κN)[1,1'-biphenyl]-2-yl-κC][dicyclohexyl[3,6-dimethoxy-2',4',6'-tris(1-methylethyl)[1,1'-biphenyl]-2-yl]phosphine-κP](methanesulfonato-κO)palladium;Methanesulfonato(2-dicyclohexylphosphino-3,6-diMethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-aMino-1,1'-biphenyl-2-yl)palladiuM(II), Min. 98% [BrettPhos Palladacycle];Methanesulfonato(2-dicyclohexylphosphino-3,6-diMethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-aMino-1,1'-biphenyl-2-yl)palladiuM(II), Min. 98%;BrettPhos Pd G3
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  • AK Scientific
  • Alfa Aesar
  • Ambeed
  • Apolloscientific
  • Arctom
  • Chemenu
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Package
  • 100mg
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  • 25g
  • ManufacturerAK Scientific
  • Product number0516AQ
  • Product descriptionBrettPhos Pd G3
  • Packaging250mg
  • Price$139
  • Updated2021-12-16
  • Buy
  • ManufacturerAlfa Aesar
  • Product number047250
  • Product descriptionBrettPhos Palladacycle 3rd Generation, 98%
  • Packaging250mg
  • Price$122
  • Updated2024-03-01
  • Buy
  • ManufacturerAlfa Aesar
  • Product number047250
  • Product descriptionBrettPhos Palladacycle 3rd Generation, 98%
  • Packaging1g
  • Price$460
  • Updated2024-03-01
  • Buy
  • ManufacturerAlfa Aesar
  • Product number047250
  • Product descriptionBrettPhos Palladacycle 3rd Generation, 98%
  • Packaging5g
  • Price$1470.65
  • Updated2024-03-01
  • Buy
  • ManufacturerAmbeed
  • Product numberA1194516
  • Product description[(2-Di-cyclohexylphosphino-3,6-dimethoxy-2′,4′,6′-triisopropyl-1,1′-biphenyl)-2-(2′-amino-1,1′-biphenyl)]palladium(II)methanesulfonate 98+%
  • Packaging100mg
  • Price$13
  • Updated2021-12-16
  • Buy
  • ManufacturerAmbeed
  • Product numberA1194516
  • Product description[(2-Di-cyclohexylphosphino-3,6-dimethoxy-2′,4′,6′-triisopropyl-1,1′-biphenyl)-2-(2′-amino-1,1′-biphenyl)]palladium(II)methanesulfonate 98+%
  • Packaging250mg
  • Price$23
  • Updated2021-12-16
  • Buy
  • ManufacturerAmbeed
  • Product numberA1194516
  • Product description[(2-Di-cyclohexylphosphino-3,6-dimethoxy-2′,4′,6′-triisopropyl-1,1′-biphenyl)-2-(2′-amino-1,1′-biphenyl)]palladium(II)methanesulfonate 98+%
  • Packaging1g
  • Price$75
  • Updated2021-12-16
  • Buy
  • ManufacturerAmbeed
  • Product numberA1194516
  • Product description[(2-Di-cyclohexylphosphino-3,6-dimethoxy-2′,4′,6′-triisopropyl-1,1′-biphenyl)-2-(2′-amino-1,1′-biphenyl)]palladium(II)methanesulfonate 98+%
  • Packaging5g
  • Price$330
  • Updated2021-12-16
  • Buy
  • ManufacturerAmbeed
  • Product numberA1194516
  • Product description[(2-Di-cyclohexylphosphino-3,6-dimethoxy-2′,4′,6′-triisopropyl-1,1′-biphenyl)-2-(2′-amino-1,1′-biphenyl)]palladium(II)methanesulfonate 98+%
  • Packaging10g
  • Price$592
  • Updated2021-12-16
  • Buy
  • ManufacturerAmbeed
  • Product numberA1194516
  • Product description[(2-Di-cyclohexylphosphino-3,6-dimethoxy-2′,4′,6′-triisopropyl-1,1′-biphenyl)-2-(2′-amino-1,1′-biphenyl)]palladium(II)methanesulfonate 98+%
  • Packaging25g
  • Price$1306
  • Updated2021-12-16
  • Buy
  • ManufacturerApolloscientific
  • Product numberOR939181
  • Product descriptionBrettPhos Pd G3 98%
  • Packaging250mg
  • Price$61
  • Updated2021-12-16
  • Buy
  • ManufacturerApolloscientific
  • Product numberOR939181
  • Product descriptionBrettPhos Pd G3 98%
  • Packaging1g
  • Price$196
  • Updated2021-12-16
  • Buy
  • ManufacturerApolloscientific
  • Product numberOR939181
  • Product descriptionBrettPhos Pd G3 98%
  • Packaging5g
  • Price$538
  • Updated2021-12-16
  • Buy
  • ManufacturerArctom
  • Product numberSY073041
  • Product descriptionMethanesulfonato(2-dicyclohexylphosphino-3,6-dimethoxy-2’,4’,6’-tri-i-propyl-1,1’-biphenyl)(2’-amino-1,1’-biphenyl-2-yl)palladium(II) ≥98%
  • Packaging250mg
  • Price$55
  • Updated2021-12-16
  • Buy
  • ManufacturerArctom
  • Product numberSY073041
  • Product descriptionMethanesulfonato(2-dicyclohexylphosphino-3,6-dimethoxy-2’,4’,6’-tri-i-propyl-1,1’-biphenyl)(2’-amino-1,1’-biphenyl-2-yl)palladium(II) ≥98%
  • Packaging1g
  • Price$135
  • Updated2021-12-16
  • Buy
  • ManufacturerArctom
  • Product numberSY073041
  • Product descriptionMethanesulfonato(2-dicyclohexylphosphino-3,6-dimethoxy-2’,4’,6’-tri-i-propyl-1,1’-biphenyl)(2’-amino-1,1’-biphenyl-2-yl)palladium(II) ≥98%
  • Packaging5g
  • Price$480
  • Updated2021-12-16
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
AK Scientific 0516AQ BrettPhos Pd G3 250mg $139 2021-12-16 Buy
Alfa Aesar 047250 BrettPhos Palladacycle 3rd Generation, 98% 250mg $122 2024-03-01 Buy
Alfa Aesar 047250 BrettPhos Palladacycle 3rd Generation, 98% 1g $460 2024-03-01 Buy
Alfa Aesar 047250 BrettPhos Palladacycle 3rd Generation, 98% 5g $1470.65 2024-03-01 Buy
Ambeed A1194516 [(2-Di-cyclohexylphosphino-3,6-dimethoxy-2′,4′,6′-triisopropyl-1,1′-biphenyl)-2-(2′-amino-1,1′-biphenyl)]palladium(II)methanesulfonate 98+% 100mg $13 2021-12-16 Buy
Ambeed A1194516 [(2-Di-cyclohexylphosphino-3,6-dimethoxy-2′,4′,6′-triisopropyl-1,1′-biphenyl)-2-(2′-amino-1,1′-biphenyl)]palladium(II)methanesulfonate 98+% 250mg $23 2021-12-16 Buy
Ambeed A1194516 [(2-Di-cyclohexylphosphino-3,6-dimethoxy-2′,4′,6′-triisopropyl-1,1′-biphenyl)-2-(2′-amino-1,1′-biphenyl)]palladium(II)methanesulfonate 98+% 1g $75 2021-12-16 Buy
Ambeed A1194516 [(2-Di-cyclohexylphosphino-3,6-dimethoxy-2′,4′,6′-triisopropyl-1,1′-biphenyl)-2-(2′-amino-1,1′-biphenyl)]palladium(II)methanesulfonate 98+% 5g $330 2021-12-16 Buy
Ambeed A1194516 [(2-Di-cyclohexylphosphino-3,6-dimethoxy-2′,4′,6′-triisopropyl-1,1′-biphenyl)-2-(2′-amino-1,1′-biphenyl)]palladium(II)methanesulfonate 98+% 10g $592 2021-12-16 Buy
Ambeed A1194516 [(2-Di-cyclohexylphosphino-3,6-dimethoxy-2′,4′,6′-triisopropyl-1,1′-biphenyl)-2-(2′-amino-1,1′-biphenyl)]palladium(II)methanesulfonate 98+% 25g $1306 2021-12-16 Buy
Apolloscientific OR939181 BrettPhos Pd G3 98% 250mg $61 2021-12-16 Buy
Apolloscientific OR939181 BrettPhos Pd G3 98% 1g $196 2021-12-16 Buy
Apolloscientific OR939181 BrettPhos Pd G3 98% 5g $538 2021-12-16 Buy
Arctom SY073041 Methanesulfonato(2-dicyclohexylphosphino-3,6-dimethoxy-2’,4’,6’-tri-i-propyl-1,1’-biphenyl)(2’-amino-1,1’-biphenyl-2-yl)palladium(II) ≥98% 250mg $55 2021-12-16 Buy
Arctom SY073041 Methanesulfonato(2-dicyclohexylphosphino-3,6-dimethoxy-2’,4’,6’-tri-i-propyl-1,1’-biphenyl)(2’-amino-1,1’-biphenyl-2-yl)palladium(II) ≥98% 1g $135 2021-12-16 Buy
Arctom SY073041 Methanesulfonato(2-dicyclohexylphosphino-3,6-dimethoxy-2’,4’,6’-tri-i-propyl-1,1’-biphenyl)(2’-amino-1,1’-biphenyl-2-yl)palladium(II) ≥98% 5g $480 2021-12-16 Buy

Properties

Melting point :150-193°C (decomposition)
storage temp. :under inert gas (nitrogen or Argon) at 2–8 °C
form :Powder
color :yellow to beige
InChIKey :ASZHREKEHVNFFW-UHFFFAOYSA-N
SMILES :P(C1CCCCC1)(C1CCCCC1)(C1C(=CC=C(OC)C=1C1C(=CC(C(C)C)=CC=1C(C)C)C(C)C)OC)[Pd+2]1(NC2=CC=CC=C2C2=CC=CC=[C-]12)[O-]S(=O)(=O)C

Safety Information

Symbol(GHS): GHS hazard pictograms
Signal word: Warning
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning GHS hazard pictograms
Precautionary statements:
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P304+P340 IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P405 Store locked up.

Description

BrettPhos Pd G3 may be used for the C-N coupling reaction between monosubstituted ureas and 1,2 dihaloaromatic system to form benzimidazolones.
It may be used in the synthesis of following compounds:
  • [Pd(cinnamyl)(BrettPhos)]OTf by reacting with [(cinnamyl)PdCl]2 and AgOTf.
  • [Pd(crotyl)(BrettPhos)]OTf by reacting with [(crotyl)PdCl]2 and AgOTf.
  • [Pd(allyl)(BrettPhos)]OTf by reacting with [(allyl)PdCl]2 and AgOTf.
  • Pd(allyl)(BrettPhos)Cl by reacting with [(allyl)PdCl]2.

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