1,3-dibromo-2-(trimethylsilyl)benzene synthesis
1synthesis methods
- Product Name:1,3-dibromo-2-(trimethylsilyl)benzene
- CAS Number:363598-42-9
- Molecular formula:C9H12Br2Si
- Molecular Weight:308.09
Yield:363598-42-9 92%
Reaction Conditions:
Stage #1: 1,3-dibromobenzenewith n-butyllithium;diisopropylamine in tetrahydrofuran;hexane at -75; for 2 h;
Stage #2: chloro-trimethyl-silane in tetrahydrofuran;hexane at -75;
References:
Mongin, Florence;Marzi, Elena;Schlosser, Manfred [European Journal of Organic Chemistry,2001,# 14,p. 2771 - 2777]