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896139-36-9

1-(4-chloropyridin-2-yl)propan-1-one synthesis

2synthesis methods
-

Yield:896139-36-9 86%

Reaction Conditions:

Stage #1: 4-chloro-pyridine-2-carbonitrile;ethylmagnesium bromide in tetrahydrofuran;diethyl ether at -15 - 20; for 5 h;Inert atmosphere;
Stage #2: with hydrogenchloride in tetrahydrofuran;water;ethylene glycol at 20; for 0.5 h;Inert atmosphere;Schlenk technique;

References:

Li, Xuezhao;Wu, Jinguo;Chen, Liyong;Zhong, Xiaoming;He, Cheng;Zhang, Rong;Duan, Chunying [Chemical Communications,2016,vol. 52,# 62,p. 9628 - 9631] Location in patent:supporting information