1-ADAMANTAN-1-YL-4,4,4-TRIFLUORO-BUTANE-1,3-DIONE synthesis
- Product Name:1-ADAMANTAN-1-YL-4,4,4-TRIFLUORO-BUTANE-1,3-DIONE
- CAS Number:758709-48-7
- Molecular formula:C14H17F3O2
- Molecular Weight:274.28
407-38-5
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$14.00/5g
1660-04-4
262 suppliers
$6.00/1g
758709-48-7
18 suppliers
$57.50/250mg
Yield:-
Reaction Conditions:
Stage #1: 1-acetyladamantanewith lithium hexamethyldisilazane in tetrahydrofuran at 0 - 20; for 0.333333 h;
Stage #2: 2,2,2-trifluoroethyl trifluoroacetate in tetrahydrofuran at 20; for 0.333333 h;
Stage #3: with ammonium chloride in tetrahydrofuran;water;
References:
Riofski, Mark V.;John, Jinu P.;Zheng, Mary M.;Kirshner, Julia;Colby, David A. [Journal of Organic Chemistry,2011,vol. 76,# 10,p. 3676 - 3683] Location in patent:experimental part
383-63-1
473 suppliers
$10.00/25g
1660-04-4
262 suppliers
$6.00/1g
758709-48-7
18 suppliers
$57.50/250mg