1-DECYL-2-METHYLIMIDAZOLE synthesis
- Product Name:1-DECYL-2-METHYLIMIDAZOLE
- CAS Number:42032-30-4
- Molecular formula:C14H26N2
- Molecular Weight:222.37
693-98-1
711 suppliers
$10.00/25g
112-29-8
397 suppliers
$6.00/25g
42032-30-4
30 suppliers
$25.00/1g
Yield:42032-30-4 75%
Reaction Conditions:
with sodium hydroxide;tetrabutylammomium bromide in toluene;
Steps:
I.a Example I
(a) preparation of 1-Decyl-2-methylimidazole Ref: Henri J.-M. Dou and Jacques Metzger, Bull. Soc. Chim. Fr. (1976) 1861 A mixture of 2-methylimidazole (12.3 g; 0.15 mol), 1-bromodecane (33.15 g; 0.15 mol), sodium hydroxide solution (69.5 ml. of 11.5M solution; 0.8 mol) and tetra-n-butylammonium bromide (1.95 g; 0.006 mol) in toluene (300 ml) was stirred rapidly for 3 hours at 65° C. After cooling to between 20° and 25° C., the toluene layer was separated and extracted with 5M HCl solution (150 ml). The extract neutralised with sodium bicarbonate and extracted many times into hexane. The hexane solution was dried over magnesium sulphate and evaporated to dryness to give an oil (25 g; 75% theory).
References:
US5620595,1997,A
1002-69-3
223 suppliers
$7.00/25g
42032-30-4
30 suppliers
$25.00/1g