1-Hydroxy-p-carborane synthesis
- Product Name:1-Hydroxy-p-carborane
- CAS Number:54360-43-9
- Molecular formula:C2HB10O
- Molecular Weight:149.13
20644-12-6
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1310-73-2
1359 suppliers
$14.00/25g
55629-27-1
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54360-43-9
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Yield:55629-27-1 96% ，54360-43-9 4%
Reaction Conditions:
with n-BuLi;trimethyl borate;H2O2 in diethyl ether;hexane;water;under Ar; n-BuLi (2.1 equiv.) in n-hexane added to carborane in ether (0°C); room temp., 1 h; B(OMe)3 (2.5 equiv.) added (-30°C); warmed (0°C, 1 h); H2O2 and HOAc added; room temp., 20 h; aq. NaHSO3 and NaOH added; room temp., 1 h; extd. with AcOEt; org. layer washed with H2O and brine; dried (MgSO4); concd.; residue purified by column chromy. (silica gel, AcOEt-n-hexane 1:5); elem. anal.;
References:
Ohta, Kiminori;Goto, Tokuhito;Yamazaki, Hiroto;Pichierri, Fabio;Endo, Yasuyuki [Inorganic Chemistry,2007,vol. 46,# 10,p. 3966 - 3970]
7647-01-0
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$10.00/10g
20644-12-6
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5796-98-5
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$475.00/100mg
54360-43-9
5 suppliers
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