ChemicalBook CAS DataBase List 1-Phenylnonane

1-Phenylnonane synthesis

14synthesis methods

Product Name:1-Phenylnonane
CAS Number:1081-77-2
Molecular formula:C15H24
Molecular Weight:204.35

100-39-0
423 suppliers
$10.00/10 g

38841-98-4
51 suppliers
$91.20/100ml

1081-77-2
83 suppliers
$41.79/10g

Yield: 88 %Chromat.

Reaction Conditions:

with C₂₀H₃₆BrN₃NiO in tetrahydrofuran at 20; for 2 h;Kumada Cross-Coupling;Reagent/catalyst;

Steps:

3.7. Typical Procedure for the Kumada Cross-Coupling Reactions in Table 1
General procedure: A vial was charged with alkyl halide substrate (0.2 mmol) and nickel catalyst (3 mol %), and theinternal standard undecane (0.2 mmol) in THF (3 mL). OctylMgCl (0.24 mmol, 2 M in THF) was thenadded dropwise at room temperature. The resulting solution was stirred at room temperature for 2 h.The reaction mixture was then filtered through a plug of silica gel and analyzed by gaschromatography. The response factor of ethyl undecanoate calibrated to the internal standard was usedto calculate product yields.

References:

Yu, Siqi;Wang, Huan;Sledziewski, Jill E.;Madhira, Venkata N.;Takahashi, Cyrus G.;Leon, Michelle K.;Dudkina, Yulia B.;Budnikova, Yulia H.;Vicic, David A. [Molecules,2014,vol. 19,# 9,p. 13603 - 13613]

629-27-6 Synthesis