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1-(TERT-BUTOXYCARBONYL)AZETIDINE synthesis
- Product Name:1-(TERT-BUTOXYCARBONYL)AZETIDINE
- CAS Number:147621-21-4
- Molecular formula:C8H15NO2
- Molecular Weight:157.21
![1-Boc-3-iodoazetidine](/CAS/20180808/GIF/254454-54-1.gif)
254454-54-1
248 suppliers
$15.00/1g
![1-(TERT-BUTOXYCARBONYL)AZETIDINE](/CAS/GIF/CB62449568.gif)
147621-21-4
42 suppliers
$52.00/100mg
Yield: 86%
Reaction Conditions:
with bismuth(III) oxide;N-ethyl-N,N-diisopropylamine;para-thiocresol in dichloromethaneIrradiation;
Steps:
9 Example 9
a), iodo compound 9 (30mg),Bismuth oxide (2.5mg, 5mol%),P-methylthiophenol (39.4 mg, 3 equiv) was weighed into a 5 mL reaction flask.Then add dichloromethane (1ml)And N,N-diisopropylethylamine (55.4 μL, 3 equiv),Reacted under 1W blue LED light,The reaction was terminated after the iodo compound 9 was consumed.Rotating to remove the reaction solvent and volatile substances,Purification by column chromatography gave Compound 9a (14.3 mg, 86%).
References:
Huazhong University of Science and Technology;Wan Qian;Zeng Jing;Wang Hao;Meng Lingkui;Zhao Xiang;Chen Wei;Tao Jinyi;Shu Penghua CN109265499, 2019, A Location in patent:Paragraph 0119; 0120; 0121
![Azetidine](/CAS/GIF/503-29-7.gif)
503-29-7
181 suppliers
$35.00/1g
![Di-tert-butyl dicarbonate](/CAS/GIF/24424-99-5.gif)
24424-99-5
821 suppliers
$13.50/25G
![1-(TERT-BUTOXYCARBONYL)AZETIDINE](/CAS/GIF/CB62449568.gif)
147621-21-4
42 suppliers
$52.00/100mg
![Azetidine](/CAS/GIF/503-29-7.gif)
503-29-7
181 suppliers
$35.00/1g
![Carbonic acid, bis(1,1-dimethylethyl) ester](/CAS/20180601/GIF/34619-03-9.gif)
34619-03-9
27 suppliers
inquiry
![1-(TERT-BUTOXYCARBONYL)AZETIDINE](/CAS/GIF/CB62449568.gif)
147621-21-4
42 suppliers
$52.00/100mg
![Di-tert-butyl dicarbonate](/CAS/GIF/24424-99-5.gif)
24424-99-5
821 suppliers
$13.50/25G
![1-(TERT-BUTOXYCARBONYL)AZETIDINE](/CAS/GIF/CB62449568.gif)
147621-21-4
42 suppliers
$52.00/100mg
![1-(Tert-butoxycarbonyl)-3-(methanesulfonyloxy)azetidine](/CAS/GIF/141699-58-3.gif)
141699-58-3
110 suppliers
$6.00/250mg
![1-(TERT-BUTOXYCARBONYL)AZETIDINE](/CAS/GIF/CB62449568.gif)
147621-21-4
42 suppliers
$52.00/100mg