1-(TRIMETHYLSILYL)-3-CHLOROBENZENE synthesis
- Product Name:1-(TRIMETHYLSILYL)-3-CHLOROBENZENE
- CAS Number:4405-42-9
- Molecular formula:C9H13ClSi
- Molecular Weight:184.74
Yield:4405-42-9 97 %Chromat.
Reaction Conditions:
Stage #1: 1-bromo-3-chlorobenzenewith n-butyllithium in tetrahydrofuran;cyclohexane at 22; for 0.25 h;Inert atmosphere;
Stage #2: chloro-trimethyl-silane in tetrahydrofuran;cyclohexane;Inert atmosphere;
References:
Slocum;Kusmic, Damir;Raber, Jeffrey C.;Reinscheld, Thomas K.;Whitley, Paul E. [Tetrahedron Letters,2010,vol. 51,# 37,p. 4793 - 4796] Location in patent:body text
108-37-2
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4405-42-9
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