2-(3-Methoxyprop-1-en-2-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane synthesis
1synthesis methods
- Product Name:2-(3-Methoxyprop-1-en-2-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
- CAS Number:1055881-27-0
- Molecular formula:C9H14BF3O2
- Molecular Weight:222.01
Yield:1055881-27-0 65 %Spectr.
Reaction Conditions:
with [1,3-bis(2,6-di-iso-propylphenyl)imidazol-2-ylidene]copper(I) tert-butoxide in tetrahydrofuran;tetrahydrofuran-d8 at 100; for 20 h;Sealed tube;Inert atmosphere;regioselective reaction;
References:
Sakaguchi, Hironobu;Uetake, Yuta;Ohashi, Masato;Niwa, Takashi;Ogoshi, Sensuke;Hosoya, Takamitsu [Journal of the American Chemical Society,2017,vol. 139,# 36,p. 12855 - 12862] Location in patent:supporting information