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ChemicalBook CAS DataBase List 2,3-Dihydro-3-(MethoxyphenylMethylene)-2-oxo-1H-indole-6-carboxylic acid Methyl ester
1160293-22-0

2,3-Dihydro-3-(MethoxyphenylMethylene)-2-oxo-1H-indole-6-carboxylic acid Methyl ester synthesis

10synthesis methods
(Z)-methyl 1-(2-chloroacetyl)-3-(methoxy(phenyl)methylene)-2-oxoindoline-6-carboxylate

1160293-24-2
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2,3-Dihydro-3-(MethoxyphenylMethylene)-2-oxo-1H-indole-6-carboxylic acid Methyl ester

1160293-22-0
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Yield:1160293-22-0 97%

Reaction Conditions:

with sodium carbonate in methanol at 63; for 0.5 h;

Steps:

5 Example 5: Preparation of methyl 3-(methoxyphenylmethylene)-2-oxoindoline-6-carboxylate
At 63 °C, 1.83g (17.27mmol) sodium carbonate was suspended in 50 ml methanol. Add together 20g (51.8mmol) methyl 1-(chloroacetyl)-3-[methoxy(phenyl)methylene]-2-oxoindoline-6-formate suspended in 400 ml of methanol. Stir for 30 min. Cool to 0 °C, and maintain 2 hours. Yellow solid are obtained after filtering the 15.54g, the target compound, the yield is 97%.

References:

Southeast University;Ji, Min;Chen, Hao;Cai, Jin;Liu, Haidong;Li, Rui 2016 Location in patent:Paragraph 0054; 0074; 0075; 0076