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1256278-61-1

Ethenol, 2,2-difluoro-1-(tributylstannyl)-, 1-(4-methylbenzenesulfonate) synthesis

1synthesis methods
Ethenol, 2,2-difluoro-1-(tributylstannyl)-, 1-(4-methylbenzenesulfonate)

1256278-61-1
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Benzenemethanol, α-(difluoromethylene)-, 1-(4-methylbenzenesulfonate)

1256278-62-2
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Yield:1256278-62-2 94%

Reaction Conditions:

with copper(l) iodide;tetrakis(triphenylphosphine) palladium(0) in N,N-dimethyl-formamide at 80; for 10 h;Inert atmosphere;

References:

Han, Seung Yeon;Jeong, In Howa [Organic Letters,2010,vol. 12,# 23,p. 5518 - 5521] Location in patent:supporting information; experimental part