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131349-34-3

Uridine, 5'-O-[bis(4-methoxyphenyl)phenylmethyl]-3'-O-[(1,1-dimethylethyl)dimethylsilyl]-, 2'-[2-cyanoethyl bis(1-methylethyl)phosphoramidite], (S)- (9CI) synthesis

1synthesis methods
81246-81-3 Synthesis
5'-O-(4,4'-DiMethoxytrityl)-3'-O-t-butyldiMethylsilyl uridine

81246-81-3
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2-cyanoethyl N,N- diisopropylchlorophosphoramidite

124482-92-4
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Uridine, 5'-O-[bis(4-methoxyphenyl)phenylmethyl]-3'-O-[(1,1-dimethylethyl)dimethylsilyl]-, 2'-[2-cyanoethyl bis(1-methylethyl)phosphoramidite], (S)- (9CI)

131349-34-3
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Yield:131349-34-3 92%

Reaction Conditions:

with N-ethyl-N,N-diisopropylamine in tetrahydrofuran at 0 - 20; for 5 h;

References:

Xu, Jianfeng;Duffy, Colm D.;Chan, Christopher K. W.;Sutherland, John D. [Journal of Organic Chemistry,2014,vol. 79,# 8,p. 3311 - 3326]