2-(Adamantan-1-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane synthesis

12synthesis methods

Product Name:2-(Adamantan-1-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
CAS Number:1357000-33-9
Molecular formula:C16H27BO2
Molecular Weight:262.2

76-09-5 Synthesis

76-09-5
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$10.00/1g

768-93-4
67 suppliers
$171.00/5g

13826-27-2
135 suppliers
$5.00/250mg

2-(Adamantan-1-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

1357000-33-9
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Yield:1357000-33-9 97%

Reaction Conditions:

Stage #1: 1-iodoadamantane;2,2'-bis(1,3,2-benzodioxaborole)with tetrabutylammonium tetrafluoroborate in N,N-dimethyl-formamide at 25; for 0.2 h;Electrolysis;Inert atmosphere;
Stage #2: 2,3-dimethyl-2,3-butane diolwith triethylamine in N,N-dimethyl-formamide at 25; for 1 h;Inert atmosphere;

References:

Wang, Bingbing;Peng, Pan;Ma, Wan;Liu, Zhao;Huang, Cheng;Cao, Yangmin;Hu, Ping;Qi, Xiaotian;Lu, Qingquan [Journal of the American Chemical Society,2021,vol. 143,# 33,p. 12985 - 12991] Location in patent:supporting information

768-90-1 Synthesis