![](/CAS/20150408/GIF/13818-44-5.gif)
2-Propenoic acid, 2-Methyl-, (2-oxo-1,3-dioxolan-4-yl)Methyl ester synthesis
- Product Name:2-Propenoic acid, 2-Methyl-, (2-oxo-1,3-dioxolan-4-yl)Methyl ester
- CAS Number:13818-44-5
- Molecular formula:C8H10O5
- Molecular Weight:186.16
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124-38-9
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106-91-2
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$6.00/25g
![2-Propenoic acid, 2-Methyl-, (2-oxo-1,3-dioxolan-4-yl)Methyl ester](/CAS/20150408/GIF/13818-44-5.gif)
13818-44-5
68 suppliers
$272.25/1g
Yield:13818-44-5 99%
Reaction Conditions:
with methyl-triphenylphosphonium iodide at 25; under 760.051 Torr; for 36 h;Time;
Steps:
General procedure for five-membered cyclic carbonate
General procedure: Methyltriphenylphosphonium iodide (20.2 mg, 0.05 mmol) was added to a solution of epoxide (1 mmol) in 1-methoxy-2-propanol (0.2 mL). The atmosphere inside the flask was replaced with CO2 (balloon, ca. 1 atm), and the reaction mixture was stirred at 25 or 45 °C. After 24-48 h, the mixture was cooled to rt, and evaporated in vacuo. The residue was purified by silica gel column chromatography (eluent: CHCl3) to give the corresponding cyclic carbonate (91-99%).
References:
Aoyagi, Naoto;Furusho, Yoshio;Endo, Takeshi [Tetrahedron Letters,2013,vol. 54,# 51,p. 7031 - 7034] Location in patent:supporting information
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![2-Propenoic acid, 2-Methyl-, (2-oxo-1,3-dioxolan-4-yl)Methyl ester](/CAS/20150408/GIF/13818-44-5.gif)
13818-44-5
68 suppliers
$272.25/1g
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931-40-8
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![2-Propenoic acid, 2-Methyl-, (2-oxo-1,3-dioxolan-4-yl)Methyl ester](/CAS/20150408/GIF/13818-44-5.gif)
13818-44-5
68 suppliers
$272.25/1g