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ChemicalBook CAS DataBase List 14-BroModaunoMycinone

14-BroModaunoMycinone synthesis

3synthesis methods
-

Yield:29742-69-6 92%

Reaction Conditions:

Stage #1: (+)-Daunomycinonewith trimethyl orthoformate in 1,4-dioxane;methanol at 20; for 0.333333 h;
Stage #2: with bromine in 1,4-dioxane;methanol;chloroform at 30; for 6 h;

References:

Rho, Young S.;Kim, Sun Y.;Kim, Wan-Joong;Yeo, Keun Yun;Hong, Sig Sin;Dong, Jin Yoo [Synthetic Communications,2004,vol. 34,# 19,p. 3497 - 3511]

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