ChemicalBook CAS DataBase List methyl 1-(6-bromonaphthalen-2-yl)cyclopropane-1-carboxylate

methyl 1-(6-bromonaphthalen-2-yl)cyclopropane-1-carboxylate synthesis

5synthesis methods

Product Name:methyl 1-(6-bromonaphthalen-2-yl)cyclopropane-1-carboxylate
CAS Number:1423703-16-5
Molecular formula:C15H13BrO2
Molecular Weight:305.17

33626-98-1 Synthesis

33626-98-1
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methyl 1-(6-bromonaphthalen-2-yl)cyclopropane-1-carboxylate

1423703-16-5
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Yield:-

Steps:

Multi-step reaction with 6 steps
1.1: lithium aluminium tetrahydride / tetrahydrofuran / 1.5 h / 0 - 20 °C
2.1: thionyl chloride; zinc(II) chloride / dichloromethane / -5 - 20 °C
3.1: acetonitrile / Reflux
4.1: sodium hydride / dimethyl sulfoxide / 2 h / 0 - 20 °C
5.1: sodium hydroxide; ethylene glycol / 72 h / 150 °C / Sealed tube
5.2: pH 2
6.1: hydrogenchloride / 3 h / Reflux

References:

WO2013/25733,2013,A1

100751-63-1
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1423703-16-5
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References

689290-84-4
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1423703-16-5
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References

305798-03-2
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1423703-16-5
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References

Cyclopropanecarbonitrile, 1-(6-bromo-2-naphthalenyl)-

1423703-12-1
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1423703-16-5
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References