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[[2-ethyl-4-[(2S,3R,4R,5S,6S)-3,4,5-trihydroxy-6-methyl-oxan-2-yl]oxy- phenyl]methylamino]methanethioic acid synthesis

10synthesis methods
Carbamothioic acid, [[4-[(2,3,4-tri-O-acetyl-6-deoxy-α-L-mannopyranosyl)oxy]phenyl]methyl]-, O-ethyl ester (9CI)

147821-50-9
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[[2-ethyl-4-[(2S,3R,4R,5S,6S)-3,4,5-trihydroxy-6-methyl-oxan-2-yl]oxy- phenyl]methylamino]methanethioic acid

147821-49-6
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Yield:147821-49-6 95%

Reaction Conditions:

with methanol;sodium methylate for 0.75 h;Ambient temperature;

References:

Leuck, Michael;Kunz, Horst [Carbohydrate Research,1998,vol. 312,# 1-2,p. 33 - 44]