Butanethioic acid, S1,S1',S1'',S1''',S1'''',S1'''''-(2,3,6,7,10,11-triphenylenehexayl) ester synthesis

1synthesis methods

Product Name:Butanethioic acid, S1,S1',S1'',S1''',S1'''',S1'''''-(2,3,6,7,10,11-triphenylenehexayl) ester
CAS Number:1586745-04-1
Molecular formula:C42H48O6S6
Molecular Weight:841.22

82632-80-2 Synthesis

2,3,6,7,10,11-hexabromobenzo[9,10]phenanthrene

82632-80-2
117 suppliers
$45.00/50mg

141-75-3
342 suppliers
$12.32/25G

Butanethioic acid, S1,S1',S1'',S1''',S1'''',S1'''''-(2,3,6,7,10,11-triphenylenehexayl) ester

1586745-04-1
0 suppliers
inquiry

Yield:1586745-04-1 67%

Reaction Conditions:

Stage #1: 2,3,6,7,10,11-hexabromo-triphenylenewith 1,3-dimethyl-2-imidazolidinone;sodium thiomethoxide at 240; for 48 h;Schlenk technique;Inert atmosphere;
Stage #2: butyryl chloride at 0; for 2 h;Schlenk technique;Inert atmosphere;

References:

Huang, Jiahong;He, Yonghe;Yao, Ming-Shui;He, Jun;Xu, Gang;Zeller, Matthias;Xu, Zhengtao [Journal of Materials Chemistry A,2017,vol. 5,# 31,p. 16139 - 16143] Location in patent:supporting information