Benzeneacetic acid, 4-(1,1-dimethylethyl)--alpha--methyl-, (S)- (9CI) synthesis

6synthesis methods

Product Name:Benzeneacetic acid, 4-(1,1-dimethylethyl)--alpha--methyl-, (S)- (9CI)
CAS Number:172824-87-2
Molecular formula:C13H18O2
Molecular Weight:206.2808

6448-13-1
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Benzeneacetic acid, 4-(1,1-dimethylethyl)--alpha--methyl-, (S)- (9CI)

172824-87-2
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Yield:172824-87-2 98%

Reaction Conditions:

with C₄₈H₅₀Cl₄N₂O₂P₂Ru₃;hydrogen;sodium hydrogencarbonate in methanol at 20; under 3750.38 Torr; for 24 h;Autoclave;enantioselective reaction;

References:

Li, Jing;Shen, Jiefeng;Xia, Chao;Wang, Yanzhao;Liu, Delong;Zhang, Wanbin [Organic Letters,2016,vol. 18,# 9,p. 2122 - 2125] Location in patent:supporting information

201230-82-2 Synthesis