4,7-Methano-1H-inden-1-amine,2,3,3a,4,7,7a-hexahydro-,[1S-(1alpha,3aalpha,4alpha,7alpha,7aalpha)]-(9CI) synthesis

3synthesis methods

Product Name:4,7-Methano-1H-inden-1-amine,2,3,3a,4,7,7a-hexahydro-,[1S-(1alpha,3aalpha,4alpha,7alpha,7aalpha)]-(9CI)
CAS Number:188000-52-4
Molecular formula:C10H15N
Molecular Weight:0

4,7-Methano-1H-inden-1-one, 3a,4,7,7a-tetrahydro-, (3aS,4R,7S,7aR)-

111136-75-5
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4,7-Methano-1H-inden-1-amine,2,3,3a,4,7,7a-hexahydro-,[1S-(1alpha,3aalpha,4alpha,7alpha,7aalpha)]-(9CI)

188000-52-4
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Yield:-

Steps:

Multi-step reaction with 4 steps
1: Zn, AcOH / ethanol / Heating
2: NaBH₄ / methanol / -78 °C
3: 94 percent / DPPA, (NCO₂Et)2, PPh₃ / tetrahydrofuran / from 0 degC to room t.
4: LiAlH₄ / tetrahydrofuran / Ambient temperature

References:

Nakada, Yoshihisa;Sugahara, Tsutomu;Ogasawara, Kunio [Tetrahedron Letters,1997,vol. 38,# 5,p. 857 - 860]

4,7-Methano-1H-inden-1-one, 2,3,3a,4,7,7a-hexahydro-, (3aR,4S,7R,7aS)-

151717-06-5
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188000-52-4
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4,7-Methano-1H-inden-1-ol, 2,3,3a,4,7,7a-hexahydro-, (1R,3aR,4S,7R,7aS)-

188000-48-8
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188000-52-4
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References