ChemicalBook CAS DataBase List [(1S)-1-(4-CHLOROPHENYL)ETHYL]METHYLAMINE

[(1S)-1-(4-CHLOROPHENYL)ETHYL]METHYLAMINE synthesis

2synthesis methods

Product Name:[(1S)-1-(4-CHLOROPHENYL)ETHYL]METHYLAMINE
CAS Number:66399-57-3
Molecular formula:C9H12ClN
Molecular Weight:169.65

Methanamine, N-[1-(4-chlorophenyl)ethylidene]-, (E)- (9CI)

53441-82-0
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[(1S)-1-(4-CHLOROPHENYL)ETHYL]METHYLAMINE

66399-57-3
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Yield:94 % ee

Reaction Conditions:

with C₃₂H₁₂BF₂₄^(1-)*C₃₃H₅₂IrN₃O₂P⁽¹⁺⁾;hydrogen in dichloromethane at 0; under 2250.23 Torr;enantioselective reaction;

References:

Salomó, Ernest;Gallen, Albert;Sciortino, Giuseppe;Ujaque, Gregori;Grabulosa, Arnald;Lledós, Agustí;Riera, Antoni;Verdaguer, Xavier [Journal of the American Chemical Society,2018,vol. 140,# 49,p. 16967 - 16970] Location in patent:supporting information

99-91-2 Synthesis

99-91-2
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66399-57-3
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References