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ChemicalBook CAS DataBase List 2-(2,6-Difluorophenyl)-N-Methoxy-N-Methylacetamide
946402-24-0

2-(2,6-Difluorophenyl)-N-Methoxy-N-Methylacetamide synthesis

1synthesis methods
85068-28-6 Synthesis
2,6-Difluorophenylacetic acid

85068-28-6
228 suppliers
$8.00/1g

6638-79-5 Synthesis
N,O-Dimethylhydroxylamine hydrochloride

6638-79-5
561 suppliers
$6.00/25g

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Yield:946402-24-0 92%

Reaction Conditions:

Stage #1: 2,6-difluorophenylacetic acidwith 1,1'-carbonyldiimidazole in tetrahydrofuran; for 1 h;Inert atmosphere;Cooling with ice;
Stage #2: N,O-dimethylhydroxylamine*hydrochloridewith N-ethyl-N,N-diisopropylamine in tetrahydrofuran;N,N-dimethyl-formamide; for 24 h;Inert atmosphere;

References:

Chou, Chun-Ming;Tung, Yu-Wen;Lin, Meng-I;Chan, Diana;Phakhodee, Wong;Isobe, Minoru [Heterocycles,2012,vol. 86,# 2,p. 1323 - 1339]